P. Munín, Francisco Reigosa, Marcos Rúa-Sueiro, J. M. Ortigueira, M. Pereira, J. M. Vila
{"title":"Synthesis and characterization of iminophosphorane palladacycles","authors":"P. Munín, Francisco Reigosa, Marcos Rúa-Sueiro, J. M. Ortigueira, M. Pereira, J. M. Vila","doi":"10.3390/ecsoc-23-06487","DOIUrl":null,"url":null,"abstract":": Herein we report on the synthesis and characterization of bisiminophosphoranes as potential tetradentate ligands. Treatment of the latter with palladium acetate gives tetranuclear structures with two ligand moieties linked by acetate-bridging ligands. The addition of ddpm (4 equivalents) provides doubly metallated structures where the phosphine acts as a bidentate chelating ligand.","PeriodicalId":20537,"journal":{"name":"Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/ecsoc-23-06487","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
: Herein we report on the synthesis and characterization of bisiminophosphoranes as potential tetradentate ligands. Treatment of the latter with palladium acetate gives tetranuclear structures with two ligand moieties linked by acetate-bridging ligands. The addition of ddpm (4 equivalents) provides doubly metallated structures where the phosphine acts as a bidentate chelating ligand.
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