Amido Pincer Nickel Catalyzed Kumada Cross-Coupling of Aryl, Heteroaryl, and Vinyl Chlorides

IF 1.7 4区 化学 Q3 CHEMISTRY, ORGANIC Synlett Pub Date : 2013-08-28 DOI:10.1055/s-0033-1339653
Xue-Qi Zhang, Zhong‐Xia Wang
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引用次数: 22

Abstract

Abstract Amido pincer nickel complexes {Ni(Cl)[2-P(Ph2)C6H4NC(Ph)=NAr]} (Ar = 4-MeC6H4, 1; Ar = 4-ClC6H4, 2; Ar = 4-MeOC6H4, 3) were shown to efficiently catalyze the cross-coupling of activated, unactivated, and deactivated aryl chlorides, N-heteroaryl chlorides, 1,4-dichlorobenzene, and vinyl chlorides with aryl Grignard reagents.
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氨基钳形镍催化芳基、杂芳基和氯乙烯的Kumada交叉偶联
氨基钳形镍配合物{Ni(Cl)[2-P(Ph2)C6H4NC(Ph)=NAr]} (Ar = 4-MeC6H4, 1;Ar = 4-ClC6H4, 2;Ar = 4- meoc6h4,3)能有效催化活化、未活化和失活芳基氯、n -杂芳基氯、1,4-二氯苯和乙烯基氯与芳基格氏试剂的交偶联。
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来源期刊
Synlett
Synlett 化学-有机化学
CiteScore
3.40
自引率
5.00%
发文量
369
审稿时长
1 months
期刊介绍: SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.
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