Distribution of sulfate‐reducing bacteria in the crevice and its effect on the initial corrosion behavior of 2205 stainless steel in artificial seawater

Zhan Zhang, T. Fang, Jiuyang Xia, Bowei Zhang, Junsheng Wu
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引用次数: 3

Abstract

In the present study, the distribution and vitality of the sulfate‐reducing bacteria (SRB) inside the crevice were characterized by scanning electron microscopy and confocal laser scanning microscopy. Potentiodynamic polarization curve tests and electrochemical impedance spectroscopy were used to evaluate the corrosion resistance. Furthermore, a starvation experiment was conducted by controlling nutrients to investigate the effects of the crevices on the transportation of nutrients and the vitality of the SRB. The results demonstrate that it was more difficult for the SRB to enter the crevice, resulting in an incomplete biofilm formed on the surface. In addition, the insufficient supply of nutrients was also the reason for the low vitality of the SRB inside the crevice. Based on these results, it was inferred that the incomplete biofilm inside the crevice acted as a micro‐galvanic, thus making the corrosion rate of 2205 stainless steel in the initial crevice corrosion much more serious than that in the open system.
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2205不锈钢在人工海水中裂缝中硫酸盐还原菌的分布及其对初始腐蚀行为的影响
本文采用扫描电镜和激光共聚焦扫描显微镜对裂缝内硫酸盐还原菌(SRB)的分布和活力进行了研究。采用动电位极化曲线试验和电化学阻抗谱法对其耐蚀性进行了评价。此外,通过控制营养物质的饥饿试验,研究了裂缝对SRB营养物质运输和活力的影响。结果表明,SRB更难进入缝隙,导致表面形成不完整的生物膜。此外,营养物质供给不足也是裂缝内SRB活力低的原因。由此可以推断,裂缝内不完整的生物膜作为微电源,使得2205不锈钢在裂缝初始腐蚀中的腐蚀速率比在开放体系中的腐蚀速率要严重得多。
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