E. Babayev, Kh.G. Efendiyeva, P. Mammadova, O.Yu. Poletayeva, I. Mukhametzyanov, Kh.Z. Behbudova
{"title":"Synthesis of s-tetramethyl–, ethylammonium-o-butylxantogenates and study of them as antimicrobial additives to lubricant-cooling fluids","authors":"E. Babayev, Kh.G. Efendiyeva, P. Mammadova, O.Yu. Poletayeva, I. Mukhametzyanov, Kh.Z. Behbudova","doi":"10.32758/2071-5951-2021-0-3-32-34","DOIUrl":null,"url":null,"abstract":"Water and emulsion lubricant-cooling fluid (LCF) are subject to microbiological damage during operation. At this time, the operation, physical-chemical, and sanitary-hygienic indicators of the LCF deteriorate and they become useless. Biocides are used as antimicrobial additives for water or water-emulsion LCFs, which also belong to the class of various organic compounds containing nitrogen and sulfur. In the present paper, a new derivative of butylxanthogenic acid was obtained from the interaction of tetramethyl-, tetraethylammonium iodine with potassium butylksantogenate. The antimicrobial properties of O-Butyl-S-tetramethyl-, tetraethylammonium xantogenate have been studied in lubricating-cooling fluid. It has been established that the O-butyl-S-tetramethyl ammoniumxantogenate has a high bactericidal, fungicidal effect in the range of 0.5-0.25-%. The structure of the substances was confirmed by IR spectroscopy.","PeriodicalId":23767,"journal":{"name":"World of Oil products the Oil Companies Bulletin","volume":"12 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"World of Oil products the Oil Companies Bulletin","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.32758/2071-5951-2021-0-3-32-34","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Water and emulsion lubricant-cooling fluid (LCF) are subject to microbiological damage during operation. At this time, the operation, physical-chemical, and sanitary-hygienic indicators of the LCF deteriorate and they become useless. Biocides are used as antimicrobial additives for water or water-emulsion LCFs, which also belong to the class of various organic compounds containing nitrogen and sulfur. In the present paper, a new derivative of butylxanthogenic acid was obtained from the interaction of tetramethyl-, tetraethylammonium iodine with potassium butylksantogenate. The antimicrobial properties of O-Butyl-S-tetramethyl-, tetraethylammonium xantogenate have been studied in lubricating-cooling fluid. It has been established that the O-butyl-S-tetramethyl ammoniumxantogenate has a high bactericidal, fungicidal effect in the range of 0.5-0.25-%. The structure of the substances was confirmed by IR spectroscopy.
水和乳化液润滑冷却液(LCF)在操作过程中容易受到微生物的破坏。此时，LCF的操作、物理化学和卫生指标恶化，变得无用。杀菌剂是水或水乳状LCFs的抗菌添加剂，也属于含氮、含硫的各种有机化合物的一类。本文通过四甲基四乙基碘铵与丁基抗氧化酸钾的相互作用，得到了一种新的丁基抗氧化酸衍生物。研究了邻丁基- s -四甲基-四乙基黄原酸铵在润滑冷却液中的抗菌性能。结果表明，o -丁基- s -四甲基氨黄原酸酯在0.5 ~ 0.25%的范围内具有较高的杀菌、抑菌效果。用红外光谱法确定了物质的结构。
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