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Development of technical requirements for the properties of automotive engine oils, taking into account trends in climate protection on the planet 考虑到地球气候保护的趋势,制定汽车发动机油性能的技术要求
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-36-40
V. Zolotov
Decarbonization of the natural environment during the operation of transport is a current trend in the world economy in recent decades. A significant increase in the number of road transport has led to its importance and an increase in its share in the increase in carbon dioxide emissions due to the use of fuels and oils. By the end of the second decade of the 21st century, emissions of carbon dioxide during the operation of transport increased by 83% and thus determined the increase in total CO2 emissions by 25% [1]. The tendency towards decarbonisation is mainly due to a significant limitation of carbon dioxide emissions from exhaust gases in piston engines and, in this regard, the properties of the used automobile engine oils. Lubricating oils perform additional functions in pure battery-powered vehicles and hybrid vehicles as opposed to vehicles powered by internal combustion engines. The amount of heat generated by electric vehicle batteries creates new demands on performance and thermal management of electric vehicles. At the same time, electric currents generated by an electric vehicle affect the performance properties of lubricants and their performance.
交通运输运行过程中自然环境的脱碳是近几十年来世界经济发展的趋势。由于使用燃料和石油,公路运输的数量大幅增加,使其变得十分重要,在二氧化碳排放量增加中所占的份额也有所增加。到21世纪第二个十年末,交通运输运行过程中的二氧化碳排放量增加了83%,从而决定了二氧化碳总排放量增加25%[1]。脱碳的趋势主要是由于活塞发动机废气中二氧化碳排放的显著限制,以及在这方面,二手汽车发动机油的特性。与内燃机驱动的汽车相比,润滑油在纯电池驱动的汽车和混合动力汽车中发挥着额外的作用。电动汽车电池产生的大量热量对电动汽车的性能和热管理提出了新的要求。同时,电动汽车产生的电流也会影响润滑油的性能和使用性能。
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引用次数: 0
MELANGETM technology of the bitumen production in one-stage without oxidation MELANGETM一段无氧化生产沥青的工艺
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-1-4-36-39
R. R. Suyunov, M. Laser
The innovative technology MELANGETM allows produce of the bitumen in one stage with the required properties, according to the technical request of the Customer, from the heavy oil residue basis on the use of physical and induced by them chemical processes. In this case, the main physical processes are heating and homogenization of various heavy residues upon heating, that is, mechanical mixing, almost to an ideal state, in parallel with the addition of a polymer capable of forming long spirals and chains in dispersed media. The experimental work was the basis for the trial production of bitumen according to the European standard BDS EN12591: 2009, which was successfully implemented using the MELANGETM technology at the LUKOIL Neftochim Burgas AD refinery (Burgas, Bulgaria). The heavy unreacted fluidized bed hydrocracking (VTB) residue of the Axens France H-oil process was used as feedstock. Based on the results of experimental work and the basis of confirmed data from the Customer, a patent of the Russian Federation No. 272118 " Method of producing road bitumen from a heavy residue" was issued. MELANGETM technology allows solving the problem of utilizing low-margin heavy oil residues, including unconverted residues from high conversion of oil residues, into high-margin products such as road bitumen and bituminous binders.
创新技术MELANGETM可以根据客户的技术要求,在使用物理和化学工艺的基础上,从重油残渣中一步生产出具有所需性能的沥青。在这种情况下,主要的物理过程是加热和加热时各种重残留物的均质化,即机械混合,几乎达到理想状态,同时加入能够在分散介质中形成长螺旋和链的聚合物。该试验工作是根据欧洲标准BDS EN12591: 2009试制沥青的基础,并在LUKOIL Neftochim Burgas AD炼油厂(保加利亚Burgas)成功实施了MELANGETM技术。以法国Axens h油工艺的重质未反应流化床加氢裂化渣油为原料。根据实验工作结果和客户确认的数据,颁发了俄罗斯联邦第272118号专利“从重渣油中生产道路沥青的方法”。MELANGETM技术可以解决利用低利润重油残渣的问题,包括高转化率油渣的未转化渣油,转化为高利润产品,如道路沥青和沥青粘合剂。
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引用次数: 0
Process flow diagram of Slavneft-YANOS PJSC Slavneft-YANOS PJSC工艺流程图
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-13-19
N. Karpov, N. N. Vakhromov, E. Dutlov, M. A. Bubnov, I. V. Gudkevich, V. Kapustin, E. Chernysheva, A. Tarasov
Novo-Yaroslavl oil refinery – now Slavneft -YANOS PJSC was commissioned in 1961, and since then has been one of the largest in russia, processing more than 15 million tons of crude oil per year. The company employs about 3000 people, including a large number of highly qualified specialists. The process of improving the process flow diagram for petroleum products production is ongoing, unique technological solutions and new processes are being introduced.
Novo-Yaroslavl炼油厂(现为Slavneft - yanos PJSC)于1961年投入使用,自那时以来一直是俄罗斯最大的炼油厂之一,每年加工超过1500万吨原油。公司现有员工约3000人,其中包括一大批高素质的专业人才。改进石油产品生产工艺流程图的过程正在进行中,独特的技术解决方案和新工艺正在引入。
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引用次数: 0
Determination of octane number in the range from 100 to 110 without use of tetraethyl lead 在不使用四乙基铅的情况下测定100至110范围内的辛烷值
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-46-49
M. Lebedev, S. Rumyantsev, T. V. Kopanskova
The reasons for the choice of toluene and isooctane blends to determine the octane number according to the research method in the range from 100 to 110 are reviewed. The data of experimental verification of operation with these blends are presented.
综述了在100 ~ 110范围内选用甲苯和异辛烷共混物确定辛烷值的原因。并给出了这些共混物运行的实验验证数据。
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引用次数: 0
Study of fractional composition change during hydrotreatment of light coker gasoil at high pressure 轻质焦化柴油高压加氢处理过程中组分变化的研究
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-36-39
A. A. Toptygin, R. I. Gudkevich, A. Morozov, E. Burov
Slavneft-YANOS PJSC plans to commission delayed coking unit in 2025, and the key task is to increase the depth of oil refining and increase the share of high-margin petroleum products. As a result of evaluating the change of 95% of the diesel fuel boiling point during hydrotreatment at high hydrogen pressure, it was concluded that it is possible to expand the fractional composition of light coker gasoil at expense of heavy coker gasoil.
Slavneft-YANOS PJSC计划在2025年投产延迟焦化装置,关键任务是增加炼油深度,增加高利润石油产品的份额。通过对柴油在高压加氢处理过程中95%的沸点变化进行评价,得出了以牺牲重质焦化柴油为代价扩大轻质焦化柴油馏分组成的可能性。
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引用次数: 0
Formulating regression equations for the virtual analyzers of the main quality factors of the alkylation process 建立了烷基化过程主要质量因素虚拟分析仪的回归方程
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-6-10
V.A. Laventjev, E. Golovina
The growth prospects of the chemical and petrochemical industries are shaped by the necessity of developing and implementing advanced technological solutions for improving operational performance of production by the effect of selecting the most suitable process parameters and predicting quality factors of the end products once very minute. The task of continuous product quality control may be successfully resolved by means of implementing an Advanced Process Control System (APCS). The functioning of APCS is based on virtual analyzers (VA) of product quality. A virtual analyzer is a mathematical model which is being developed with reference to long-time statistics of lab collected and performance data. Virtual analyzers facilitate assessing the desired, rather than directly measured, product quality factors by product parameters which are under continuous control by means of advanced control systems. The article describes an approach to developing a system of virtual analyzers for target quality factors of alkylphenols based on regression equations that have been formulated by the least-squares method.
通过选择最合适的工艺参数和每分钟预测一次最终产品的质量因素,开发和实施先进技术解决方案的必要性决定了化学和石化工业的增长前景。通过实施先进过程控制系统(APCS),可以成功地解决持续产品质量控制的任务。APCS的功能建立在产品质量虚拟分析仪(VA)的基础上。虚拟分析仪是根据实验室采集的长期统计数据和性能数据开发的一种数学模型。虚拟分析仪便于通过产品参数评估所需的产品质量因素,而不是直接测量,产品参数通过先进的控制系统进行连续控制。本文介绍了一种基于最小二乘回归方程的烷基酚目标品质因子虚拟分析仪系统的开发方法。
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引用次数: 0
The Effect of Inorganic Solid Particles and Water on the Results of a Sulfur Content Measurement in Crude Oil with an X-ray Fluorescence Spectrometry 无机固体颗粒和水对x射线荧光光谱法测定原油中硫含量结果的影响
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-42-48
M. Tyumentsev, A. V. Grigoriev
The petroleum refining industry requires an accurate sulfur content determination in crude oil which is often achieved by applying energy dispersive X-ray fluorescence spectrometry (EDXRF). This analytical method provides fast and precise determination of total sulfur content in crude oil and petroleum products. However, the presence of large quantities of inorganic solid particles and/or dispersed water in the crude oil samples to be analyzed may lower the results of sulfur content measurements. It was established that a decrease of the results of sulfur content measurements in crude oil depends on the quantities of water and inorganic solid particles in the samples to be analyzed, and, to a large extent, on the position of a sample in the analyzer. The effects of these factors on the results of sulfur content measurements in the crude were assessed quantitatively. It was demonstrated that the sample-surface-side geometry of the analyzer is more efficient than the sample-surface-down geometry since it drastically reduces the adverse effects of water and inorganic solid particles on the results of sulfur content measurements in crude oil.
石油炼制工业需要精确测定原油中的硫含量,这通常通过应用能量色散x射线荧光光谱法(EDXRF)来实现。该方法可快速、准确地测定原油及石油产品中总硫含量。然而,在待分析的原油样品中存在大量的无机固体颗粒和/或分散的水可能会降低硫含量测量的结果。确定了原油硫含量测量结果的降低取决于待分析样品中水和无机固体颗粒的数量,并且在很大程度上取决于样品在分析仪中的位置。定量评价了这些因素对原油含硫量测定结果的影响。结果表明,该分析仪的样品表面侧几何结构比样品表面朝下几何结构更有效,因为它大大减少了水和无机固体颗粒对原油硫含量测量结果的不利影响。
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引用次数: 0
Laboratory unit for evaluation of hydrogen sulfide additives-absorbers efficiency 评价硫化氢添加剂-吸收剂效率的实验室装置
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-4-50-52
S. Rumyantsev, A. Orlov, Ya. A. Kharchenko, N. V. Smirnov, D. V. Cherniy, G. B. Chubarov
The article describes a method for efficiency determination of hydrogen sulfide additives-absorbers used to reduce its concentration in the production of commercial fuel oil (mazut). The diagram and design of the labo-ratory unit are proposed. The method can be implemented in any refinery laboratory.
本文介绍了在工业燃料油(mazut)生产中用于降低硫化氢浓度的硫化氢添加剂-吸收剂的效率测定方法。提出了实验单元的框图和设计方案。该方法适用于任何炼油厂实验室。
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引用次数: 0
Features of production and application of sulfonate greases 磺酸脂的生产特点及应用
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-50-56
O. Kalyanova, A. V. Peskovets, I. Tatur, L. Bagdasarov
The main trends in the use of modern greases are analyzed and the most promising ones are identified. The properties and structure of sulfonate greases with different alkalinity and their application areas are considered. The technologies and equipment used for the production of sulfonate greases with thickeners obtained by various methods are presented. Sulfonate greases can become "universal", due to their operational and physico-chemical characteristics. It is noted that a large number of studies of sulfonate greases have been conducted, but they are mainly related to the study of their structure and water absorption capacity. In this regard, additional studies of the protective and low-temperature properties of sulfonate greases based on various dispersed media, as well as the study of their tribological parameters at high temperatures, are needed.
分析了现代润滑脂使用的主要趋势,并确定了最有前途的润滑脂。讨论了不同碱度的磺酸盐润滑脂的性能、结构及其应用领域。介绍了用各种方法获得的增稠剂生产磺酸脂的工艺和设备。由于其操作和物理化学特性,磺酸脂可以成为“通用”。值得注意的是,人们对磺酸脂进行了大量的研究,但主要是对其结构和吸水能力的研究。在这方面,需要进一步研究基于各种分散介质的磺酸盐润滑脂的保护性能和低温性能,以及研究其在高温下的摩擦学参数。
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引用次数: 1
Upgrading of Heavy Oil under the exposition of Supercritical Water at Different Temperatures 不同温度超临界水作用下重油的提质研究
Pub Date : 2021-01-01 DOI: 10.32758/2071-5951-2021-0-3-12-21
R. Djimasbe, M. Varfolomeev, A.A. Al-Muntasser, M.A. Suweid, Y. Osin, F. Diop, A. Mustafina, D.I. Garaeva
In this work, an experimental study of the upgrading of heavy oil under the influence of supercritical water (SCW) at temperatures of 380 °C, 420 °C and 440 °C was carried out. The analysis of the composition and properties of liquid and solid products was carried out using a set of methods including SARA analysis, gas chromatography (GC), IR spectroscopy, scanning electron microscopy (SEM), and energy-dispersive X-ray fluorescence spectrometry. The results show that with increase of the SCW temperature, an increase in the amount of gaseous products and coke occurs, while the yield of liquid products, their viscosity and density decrease. Data from SARA analysis and gas chromatography showed that with the increase of temperature to 420 °C, the content of the fraction of resins and asphaltenes decreases and the amount of saturated hydrocarbons increases to a maximum value. Similarly, at 420 °C, the vanadium (V) content decreases by 61.66 % in heavy oil, where it should be noted that the vanadium content is very sensitive to temperature changes. The elemental analysis data confirm that, under the influence of SCW, the sulfur content in oil decreases from 4.21 % to 2.43 %. According to the results obtained, it can be noted that the choice of temperature under the action of SCW significantly affects the upgrading of heavy oil. The most optimal temperature for the investigated heavy oil is 420 °C. The use of SCW is of practical interest for upgrading heavy oil, including reservoir conditions.
在380℃、420℃和440℃条件下,对超临界水(SCW)对稠油的提质进行了实验研究。采用SARA分析、气相色谱(GC)、红外光谱(IR)、扫描电镜(SEM)和能量色散x射线荧光光谱等方法对液体和固体产物的组成和性质进行了分析。结果表明:随着工艺温度的升高,气态产物和焦炭的数量增加,液态产物的产率、粘度和密度降低;SARA分析和气相色谱分析数据表明,随着温度升高至420℃,树脂和沥青质组分含量降低,饱和烃含量达到最大值。同样,在420℃时,重油中钒(V)含量下降了61.66%,需要注意的是,钒含量对温度变化非常敏感。元素分析数据证实,在超临界水的作用下,原油含硫量从4.21%下降到2.43%。结果表明,超临界水作用下温度的选择对稠油的提质有显著影响。稠油的最佳温度为420℃。对于稠油的改造,包括储层条件,超临界水的使用具有实际意义。
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引用次数: 2
期刊
World of Oil products the Oil Companies Bulletin
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