Structural and dielectric properties of Na0.7Bi0.3TiO3

S. Dagar, Ashima Hooda, D. Ahlawat, N. Sharma, S. Khasa
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Abstract

Na0.7Bi0.3TiO3 pervoskite were developed through solid state reaction method. The formation of rhombohedral crystal structure was confirmed from the XRD and rietveld refinement. Dielectric properties of the sample were studied in the frequency range 1kHz to 5MHz in temperature range from room temperature to 400°C. Dielectric constant and tangent loss increases with increase in temperature and decrease with increase in frequency for prepared composition. AC conductivity pattern obey Jonscher’s power law and appears nearly constant at lower frequencies and increases at higher frequencies. Dc conductivity and corresponding activation energy for the prepared composition were measured. DC conductivity obeys Arrehenius relation. Dc conductivity and activation energy increases as temperature increases.
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Na0.7Bi0.3TiO3的结构和介电性能
采用固相反应法制备了Na0.7Bi0.3TiO3钙钛矿。通过XRD和rietveld细化,证实了该材料形成了菱形晶体结构。在室温至400℃的温度范围内,研究了样品在1kHz至5MHz的频率范围内的介电性能。在所制备的组合物中,介电常数和切线损耗随温度的升高而增大,随频率的增加而减小。交流电导率模式服从琼舍尔幂定律,在较低频率下几乎不变,在较高频率下增加。测定了所制备组合物的直流电导率和相应的活化能。直流电导率服从阿雷尼乌斯关系。直流电导率和活化能随温度升高而增大。
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