Characterization and Study of a Gas Sensor Based on SnO2 Pellets for Differentiation Biodiesel Blends

L. Castañeda
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Abstract

SnO2 pellets with surface gold interdigitated electrodes was obtained and used in the differentiation of biodiesel blends. The tin oxide synthesis method was polymeric precursor with further thermal treatment at 500 °C to eliminate organic part, conformed and sintered at three temperatures: 700° (Sn1), 900° (Sn2) and 1100 °C (Sn3). The samples were studied by X-ray Diffraction, FEG-SEM (Field Emission Gun-Scanning Electron Microscopy), Raman spectroscopy and electrical sensing gas measurements. The characterization techniques confirm the phase cassiterite (tetragonal type rutile structure), and particles with aspects almost spherical with particles size among 30 and 90 nm, Raman vibrational modes are characteristic of tin dioxide in rutile phase. The sensorial measurements showed high sensitivity in the tests with mixtures biodiesel/Ethanol allowing to distinguish the blends, but not well distinguished the blend diesel/biodiesel.
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基于SnO2颗粒的生物柴油气体传感器的表征与研究
制备了表面金互指电极的SnO2球团,并将其用于生物柴油混合物的鉴别。合成氧化锡的方法是采用聚合物前驱体,在500℃下进一步热处理去除有机部分,在700℃(Sn1)、900℃(Sn2)和1100℃(Sn3)三个温度下进行配形和烧结。采用x射线衍射、场发射枪扫描电镜(FEG-SEM)、拉曼光谱和电传感气体测量对样品进行了研究。表征技术证实了锡石相(四方型金红石结构),晶粒尺寸在30 ~ 90 nm之间,几乎为球形,拉曼振动模式是金红石相二氧化锡的特征。在生物柴油/乙醇混合物的测试中,感官测量显示出较高的灵敏度,可以区分混合物,但不能很好地区分混合柴油/生物柴油。
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来源期刊
Sensor Letters
Sensor Letters 工程技术-电化学
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审稿时长
6 months
期刊介绍: The growing interest and activity in the field of sensor technologies requires a forum for rapid dissemination of important results: Sensor Letters is that forum. Sensor Letters offers scientists, engineers and medical experts timely, peer-reviewed research on sensor science and technology of the highest quality. Sensor Letters publish original rapid communications, full papers and timely state-of-the-art reviews encompassing the fundamental and applied research on sensor science and technology in all fields of science, engineering, and medicine. Highest priority will be given to short communications reporting important new scientific and technological findings.
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