Design and Development of a Novel Fluid Loss Additive for Invert Emulsion Drilling Fluids from a Renewable Raw Material

S. Maghrabi, Delores Smith, A. Engel, Jennifer Henry, Joseph Fandel
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引用次数: 2

Abstract

Commonly used fluid loss additives (FLAs) in today's invert emulsion drilling fluids include materials with various attributes. The unmet needs of existing materials may include: Environmental restrictions due to ecotoxicity or biodegradability concernsPerformance issues at high temperaturesOverdosing at high temperaturesHigh costsFormation damage To address these challenges, a FLA was developed for invert emulsion drilling fluids that is made from a renewable raw material and performs at high temperature and high pressure. The renewable raw material used to make this novel FLA is a biopolymer byproduct of the paper pulping process, and was chemically modified under controlled conditions to create a high-performing FLA. Detailed testing was done to determine the additive's performance in different base oils (mineral and diesel), at various mud weights (12 to 16 ppg), at elevated temperatures and in different fluid systems characterized by rheology and high-pressure, high-temperature (HPHT) fluid loss. The novel FLA was compared to other commercially available FLAs for fluid loss performance. The novel FLA outperformed or was on par with the industry available FLAs tested in this study. The novel FLA realized comparable fluid loss performance of less than 10 ml at 375 F at lower concentrations as compared to the industry FLAs. In some cases, the novel FLA performed at higher temperatures, whereas some of the industry available FLAs did not. The novel FLA also boosted the electrical stability (ES) of the emulsion in certain fluid systems. The novel FLA showed minimum change in the rheology of the oil-based fluids as compared to the industry available FLAs. The novel FLA demonstrated reasonable performance in different mud weights, base oils and fluid systems. Since this novel FLA is derived from a renewable raw material, it may have less of an environmental impact compared to other FLAs utilized today. The novel FLA: Was developed from a renewable raw material for invert emulsion drilling fluids;Performed on par or outperformed industry available FLAs; andBoosted the ES of the emulsion for certain fluid systems.
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新型反乳化钻井液降滤失剂的设计与研制
在当今的反乳化钻井液中,常用的滤失剂(FLAs)包括各种属性的材料。现有材料的未满足需求可能包括:生态毒性或生物降解性对环境的限制;高温下的性能问题;高温下的过量剂量;高成本;地层损害为了解决这些挑战,开发了一种由可再生原料制成的反乳化钻井液FLA,该钻井液可在高温高压下工作。用于制造这种新型FLA的可再生原料是造纸过程的生物聚合物副产品,并在受控条件下进行化学改性以制造高性能FLA。为了确定添加剂在不同基础油(矿物油和柴油油)、不同泥浆比重(12 ~ 16 ppg)、高温下的性能,以及在不同流变性和高压高温(HPHT)滤失流体体系中的性能,研究人员进行了详细的测试。将新型滤失剂与其他市售滤失剂的滤失性能进行了比较。该新型FLA的性能优于或与本研究中测试的行业可用FLA相当。与工业FLAs相比,新型FLAs在375华氏度和较低浓度下实现了小于10 ml的失液性能。在某些情况下,新型FLA可以在更高的温度下工作,而一些工业上可用的FLA则不能。新型FLA还提高了乳液在某些流体体系中的电稳定性(ES)。与现有的FLAs相比,新型FLAs对油基流体流变学的影响最小。新型FLA在不同泥浆比重、基础油和流体体系中均表现出合理的性能。由于这种新型FLA来源于可再生原料,与目前使用的其他FLA相比,它对环境的影响可能更小。新型FLA:由可再生原料开发而成,用于反乳化钻井液,性能与行业现有的FLA相当或优于后者;提高了乳状液在某些流体体系中的ES。
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