Yuting Chen , Guanghui Lv , Zhiyang Li , Meiling Ye , Tianle Huang , Li Hai , Yong Wu
{"title":"Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides","authors":"Yuting Chen , Guanghui Lv , Zhiyang Li , Meiling Ye , Tianle Huang , Li Hai , Yong Wu","doi":"10.1016/j.gresc.2023.04.004","DOIUrl":null,"url":null,"abstract":"<div><p>The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp<sup>3</sup>)-S and C(sp<sup>3</sup>)-Se bond with broad substrate scope and great functional group tolerance.</p></div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 2","pages":"Pages 77-79"},"PeriodicalIF":0.0000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666554923000339/pdfft?md5=d974594596fdf40dc9b7f441e906f029&pid=1-s2.0-S2666554923000339-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Synthesis and Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666554923000339","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate scope and great functional group tolerance.