{"title":"Influence of reaction conditions on the selectivity of the process of epoxidation of oct-1-ene by tert-butyl hydroperoxide in the presence of МоВ","authors":"M. Zhukrovska, Z. Komarenska","doi":"10.23939/ctas2023.01.022","DOIUrl":null,"url":null,"abstract":"The influence of the reaction conditions on the selectivity of the interaction of oct-1-ene with tert-butyl hydroperoxide in the presence of MoB was investigated. It is shown that the selectivity of 1,2-epoxyoctane formation can vary depending on the reaction conditions.With the participation of the activated form of the catalyst, the selectivity increases significantly, but does not reach 100%. The optimal reaction conditions under which the selectivity of 1,2-epoxyoctane formation exceeds 90% have been established.","PeriodicalId":9808,"journal":{"name":"Chemistry, Technology and Application of Substances","volume":"5 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry, Technology and Application of Substances","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.23939/ctas2023.01.022","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The influence of the reaction conditions on the selectivity of the interaction of oct-1-ene with tert-butyl hydroperoxide in the presence of MoB was investigated. It is shown that the selectivity of 1,2-epoxyoctane formation can vary depending on the reaction conditions.With the participation of the activated form of the catalyst, the selectivity increases significantly, but does not reach 100%. The optimal reaction conditions under which the selectivity of 1,2-epoxyoctane formation exceeds 90% have been established.