The Study of the Influence of Chemical Nature of Functional Groups in Oligomeric and Low--Molecular Modifiers on the Rheological Properties of the Epoxy Oligomer

E. Barabash, Sumska St. Kharkiv Ukraine Architecture, Y. Popov, Y. Danchenko
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引用次数: 1

Abstract

The influence of chemical nature of modifier functional groups on the level of intermolecular interactions in the system "epoxy oligomer ‒ modifier", as well as the structure formation and dynamic viscosity of epoxy oligomer has been studied in detail. Modifying additives in low concentrations contribute to an increase in the degree of structure formation of the epoxy system by increasing the intermolecular interaction between the associates of the epoxydiane oligomer. It was established that the strength of the formed coagulation structures depends both on the compatibility parameter of the modifiers and ED-20, and on their intermolecular interaction energy.
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低聚和低分子改性剂中官能团的化学性质对环氧低聚物流变性能影响的研究
详细研究了改性剂官能团的化学性质对“环氧低聚物-改性剂”体系分子间相互作用水平的影响,以及环氧低聚物的结构形成和动态粘度的影响。低浓度的改性添加剂通过增加环氧二烯低聚物的缔合物之间的分子间相互作用,有助于增加环氧体系的结构形成程度。结果表明,所形成的混凝结构的强度既取决于改性剂与ED-20的相容性参数,也取决于它们的分子间相互作用能。
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