Multifunctional Chemical for Simultaneous Dissolution of Iron Sulfide, Corrosion Inhibition, and Scale Inhibition

P. Rodgers, Brian J. Lundy, S. Ramachandran, Jim Ott, David J. Poelker, Dong Lee, Corey Stevens, C. Bounds, Matthew Sullivan
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Abstract

Operators producing hydrocarbons from conventional and unconventional wells often encounter interconnected production-related challenges that exacerbate one another. Challenges during production include the corrosion of steel caused by acid gases, as well as the precipitation and accumulation of iron sulfide, calcium carbonate scale, and barium sulfate scale. The accumulation of solids on pipe walls can facilitate under-deposit corrosion and plugging. Each of these issues can lead to failures and costly workovers. To address these issues, current treatment approaches require multiple chemical applications, frequent batch treatments, mechanical intervention, or a combination of approaches. In certain scenarios, these approaches can be impractical, ineffective, and/or uneconomical. The objective of this study was to develop a solution to overcome the aforementioned production challenges simultaneously and continuously with a single chemical application. The design strategy was to formulate chemicals that included a variety of chemistries to inhibit multiple corrosion mechanisms, as well as an iron sulfide dissolver, and a scale inhibitor to inhibit the formation of calcium carbonate and barium sulfate scales. Laboratory tests were conducted to demonstrate that the formulations could function in the aforementioned areas. One formulation was then applied in the field under different production scenarios: oil wells equipped with either a gas lift mechanism or an electrical submersible pump. Data from those situations are presented to demonstrate the field performance of the new formulation. Compared to the benchmark chemical treatment efforts, application of the formulation improved or maintained similar corrosion control, reduced or eliminated the accumulation of iron sulfide solids in the well, and improved scale control in each of the production scenarios. This paper presents a viable option for effectively treating common production challenges simultaneously and with one chemical application, which is particularly useful when it is impractical or uneconomical to employ multiple chemical treatments.
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同时溶解硫化铁,缓蚀和阻垢的多功能化学品
从常规井和非常规井中生产碳氢化合物的运营商经常遇到相互关联的生产相关挑战,这些挑战相互加剧。生产过程中的挑战包括酸性气体对钢的腐蚀,以及硫化铁、碳酸钙结垢和硫酸钡结垢的沉淀和积累。固体物质在管壁上的积聚会导致沉积下腐蚀和堵塞。这些问题都可能导致失败和昂贵的修井作业。为了解决这些问题,目前的处理方法需要多种化学应用、频繁的批量处理、机械干预或多种方法的组合。在某些情况下,这些方法可能不切实际、无效和/或不经济。本研究的目的是开发一种解决方案,以克服上述生产挑战,同时持续使用单一化学品。设计策略是配制化学物质,包括多种化学物质,以抑制多种腐蚀机制,以及硫化铁溶解剂和阻垢剂,以抑制碳酸钙和硫酸钡鳞片的形成。进行了实验室试验,以证明这些制剂可以在上述领域发挥作用。然后在不同的生产场景下应用了一种配方:配备气举机构或电动潜水泵的油井。从这些情况的数据提出,以证明新配方的现场性能。与基准化学处理相比,该配方的应用改善或保持了类似的腐蚀控制,减少或消除了硫化铁固体在井中的积聚,并改善了每种生产情况下的结垢控制。本文提出了一种可行的选择,可以同时有效地处理常见的生产挑战,并且使用一种化学方法,当使用多种化学方法不切实际或不经济时,这种方法特别有用。
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