USE OF BIS-ADDUCTS OF ETHANEDITHIOL WITH ALKYL- AND CYCLOALKYL SUBSTITUTED METHYLENE DIOXOLANES IN THE COMPOSITION OF POLYVINYL CHLORIDE

F.Kh. Yusifli, N. Aliyeva, G. Ramazanov
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Abstract

By free radical addition of ethanedithiol to alkyl- and cycloalkyl-substituted methylene dioxolanes, the bis-adducts tested then as a plasticizer for PVC have been obtained. It has been established as a result of the carried out investigations that the introduction of the synthesized compounds into PVC composition improves the physical-mechanical properties, which has been connected with the availability of sulfur atoms, carbonyl groups and ether bond in the molecules of bis-adducts. The high operational indices from PVCplastics indicate good plasticizing properties of the synthesized bis-adducts, and therefore they can be recommended for practical use.
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乙二硫醇与烷基和环烷基取代的亚甲基二氧索烷双加合物在聚氯乙烯合成中的应用
将乙二硫醇自由基加成到烷基取代和环烷基取代的亚甲基二氧索烷中,得到了用于PVC增塑剂的双加合物。研究结果表明,将合成的化合物引入PVC组合物中可以改善PVC的物理力学性能,这与双加合物分子中硫原子、羰基和醚键的可用性有关。聚氯乙烯的操作指标较高,表明合成的双加合物具有良好的增塑性,可推荐用于实际应用。
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