Effect of Cationic Surfactant in the Synthesis Process of Nano γ-Alumina for Petroleum Industry Application

Mustafa H. Flayyih, Mohammed S. Theib
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Abstract

    Nanotechnology is widely used in industries, including catalyst synthesis for oil and gas industries to enhance and perform new Characteristics of materials. Cetyl tri methyl ammonium bromide (CTAB) cationic surfactant was used in the synthesis of spherical nanostructured γ-alumina to enhance the morphology of the prepared nano gamma alumina which is used as a catalyst support in the naphtha reforming process. The preparation was carried out by co-precipitation method by adding drop wise of ammonium hydroxide solution and aluminum nitrate nonahydrate solution simultaneously to a solution of surfactant medium, PH and temperature of reaction were kept at 8 and 30 cᵒ respectively. The gamma alumina obtained were characterized by X- Ray Diffraction (XRD), nitrogen adsorption-desorption analysis (ASAP 2020, Micromeretics) and atomic force microscope (AFM). The sample of synthesized gamma alumina with the CTAB cationic surfactant showed that surface are (314 m2/g), pore volume (0.37 cm3/g), and pore size (3.6 nm).
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阳离子表面活性剂在石油工业用纳米γ-氧化铝合成过程中的作用
纳米技术广泛应用于工业,包括石油和天然气工业的催化剂合成,以增强和实现材料的新特性。采用十六烷基三甲基溴化铵(CTAB)阳离子表面活性剂合成球形纳米γ-氧化铝,以改善纳米γ-氧化铝的形貌,并将其作为石脑油重整过程的催化剂载体。采用共沉淀法,将氢氧化铵溶液和硝酸铝非水合溶液同时滴入表面活性剂介质溶液中,反应PH为8℃,反应温度为30℃。采用X射线衍射(XRD)、氮吸附-解吸分析(ASAP 2020, Micromeretics)和原子力显微镜(AFM)对所制得的γ氧化铝进行了表征。用CTAB阳离子表面活性剂合成的γ -氧化铝样品的表面表面积为314 m2/g,孔体积为0.37 cm3/g,孔径为3.6 nm。
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