Impact of H2S Content and Excess Air on Pollutant Emission in Sour Gas Flares

Abstract

In sour gas flares,  content like any other components in inlet gas influences adiabatic flame temperature, which, in turn, impacts on the pollutant emission. Wherever flame temperature increases, the endothermic reaction between  and  is accelerated, which means higher  emission to the atmosphere. In this work, we developed an in-house MATLAB code to provide an environment for combustion calculations. Then, this written code was used to perform sensitivity analyses on  content, air temperature, and excess air ratio in sour gas flares. We used Environmental Protection Agency (EPA) reports to assign weighting indexes to each air contaminant according to its harmfulness to environment; thereafter, sour gas flaring conditions were optimized for two real field case studies, namely Ahwaz (AMAK) and South Pars, to reach the minimum integrated pollutant concentrations. The results show that each 2% increase in the  content of the entrance feed may produce 0.3% additional  in the exhaust. The results also confirm that decreases of 20 °F and 50 °F in the oxidant temperature cause  emission to reduce by 0.5% to 1% respectively. Finally, to verify and validate our results acquired from the written MATLAB code, FRNC 2012 industrial software was used to duplicate the oxidation results for the two sour flare case studies.