Qiong Wu, Xiangqing Zhu, Hai Yang, He Ping, Jinglong Luo, Z. Ying, Hai Wang, Quanshui Fan, E. Wang
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引用次数: 0
Abstract
By combination of β-octamolybdate and Metal-Schiff-base complex, a new organic-inorganic hybrid compound Na2[Mn(Salen)(H2O)2]2[β-Mo8O26]·3H2O (1) (sa-len=N, N'-ethylene-bis(salicylideneiminate)) has been successfully isolated. Compound 1 was structurally characterized by elemental analyses, IR spectra, thermogravimetric analysis, and single-crystal X-ray diffraction. Compound 1 represents a rare example of single-crystal structured of metal-Schiff-base derivatives of polyoxometalates(POMs). Photocatalytic experiment indicated that 1 exhibited high catalytic activity for photodegradation of RhB with UV irradiation.
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