Fingerprint Intermolecular Interactions of Sodium and Potassium Complexes

M. Bhavya, R. Malarvizhi
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Abstract

The complex of sodium and potassium salts is characterized by using UV-Visible, FT-IR, NMR, Singlecrystal X-ray diffraction, Hirshfeld surfaces, and Fingerprint plots. The crystal belongs to the monoclinic system and p121/n1, p21/n space group. The corresponding peaks for chlorine atoms are absent in the NMR spectra of the complexes. The small red spot in Hirshfeld surfaces indicates the presence of CH...π interactions in the sodium complex. Absence of Metal...Metal interactions were also observed in both sodium and potassium complex. Fingerprint plots of Hirshfeld surfaces were used to detect and examine the percentage of hydrogenbonding interactions.
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钠和钾配合物分子间相互作用的指纹图谱
通过紫外可见光谱、红外光谱、核磁共振光谱、单晶x射线衍射、赫希菲尔德表面和指纹图谱对钠钾盐配合物进行了表征。晶体属于单斜晶系和p121/n1、p21/n空间群。在配合物的核磁共振光谱中没有氯原子的相应峰。赫希菲尔德表面的小红点表明CH的存在。钠络合物中的π相互作用。缺金属……在钠和钾络合物中也观察到金属相互作用。赫希菲尔德表面的指纹图谱用于检测和检验氢键相互作用的百分比。
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