Study on the volatile organic compounds removal with mesoporous catalysts made from solar panel

C. Chang, Ri-Tian Ruan
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Abstract

In this research, the adsorption of toluene was tested with MCM-41 and mesoporous silica materials synthesized from spent solar panel and glass. The synthesized solution was mixed with cationic cetyltrimethyl ammonium bromide (CTAB) surfactants. The prepared adsorbents were characterized by nitrogen adsorption-desorption analysis, transmission electron microscope, scanning electron microscope - energy dispersive spectroscopy, X-ray powder diffractometer and Fourier transform infrared spectroscopy. The results showed that the surface area, large pore volume and pore diameter could be up to 1280m2 g-1, 0.82cm3 g-1 and 2.62 nm, respectively. The crystal patterns of mesoporous silica materials were similar of MCM-41 from TEM image. In this study, the effects of operation parameters, such as contact time and mixture concentration, on adsorption performance were also assessed.
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太阳能板介孔催化剂去除挥发性有机化合物的研究
本研究用MCM-41和由废太阳能电池板和玻璃合成的介孔二氧化硅材料对甲苯的吸附进行了测试。合成的溶液与阳离子十六烷基三甲基溴化铵(CTAB)表面活性剂混合。采用氮吸附-解吸分析、透射电镜、扫描电镜-能谱、x射线粉末衍射仪和傅里叶变换红外光谱对制备的吸附剂进行了表征。结果表明,该材料的比表面积可达1280m2 g-1,大孔体积可达0.82cm m3 g-1,孔径可达2.62 nm。TEM图像显示,介孔二氧化硅材料的晶型与MCM-41相似。在本研究中,还评估了操作参数(如接触时间和混合物浓度)对吸附性能的影响。
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