Double Pulse LIBS of Titanium-Based PVD-Coatings with Submicron Resolution

K. Ermalitskaia, E. Voropay
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Abstract

The possibility for double pulse LIBS in the process of a direct layer-by-layer analysis of the titanium-based PVD-coatings on polished flat blank samples of steel and silicon and also of the TiAlN/TiN-coating on a milling cutter is considered. A method is proposed to control thickness of the radiation evaporated layer by defocusing the laser beam with respect to the surface, making it possible to attain the depth resolution of 0.1 μm. The Ti and Ti-Zr-coatings produced using the ion-assisted condensation method and subjected to streams of the nitrogen plasma in a magnetic-plasma compressor are studied.
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亚微米分辨率钛基pvd涂层的双脉冲LIBS
在对抛光后的钢和硅的平面空白样品上的钛基pvd涂层和铣刀上的TiAlN/ tin涂层进行逐层直接分析的过程中,考虑了双脉冲LIBS的可能性。提出了一种通过使激光束相对于表面离焦来控制辐射蒸发层厚度的方法,使其可以达到0.1 μm的深度分辨率。研究了离子辅助冷凝法制备的Ti和Ti- zr涂层,并对其进行了磁等离子体压缩机中氮等离子体流的处理。
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