Optical properties of transparent nanocrystalline yttria stabilized zirconia

IF 4.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Optical Materials Pub Date : 2009-11-01 DOI:10.1016/j.optmat.2009.06.004
J.E. Alaniz, F.G. Perez-Gutierrez, G. Aguilar, J.E. Garay
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引用次数: 119

Abstract

The optical properties of transparent nanocrystalline zirconia produced using a current activated method were characterized over the entire visible spectrum. The resolutions of the samples were characterized using standard resolution targets. All of the samples produced were found to have as high a resolution as detectable from the test, i.e., they are transparent not translucent. Transmission, reflectance, and absorption coefficients are reported for various wavelengths. The absorption coefficients were found to be highly dependent on processing time. Annealing experiments helped determine that oxygen vacancies (with free electrons) are the primary absorption centers in the visible wavelengths. In addition it was found that grain boundary cores or their associated defects do not contribute significantly to light absorption in the visible range. The lack of an influence of the grain boundary regions is discussed in terms of low oxygen vacancy concentration in the grain boundary space charge layer.

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透明纳米晶氧化钇稳定氧化锆的光学性质
采用电流活化法制备的透明纳米氧化锆的光学性质在整个可见光谱上进行了表征。采用标准分辨率标靶对样品的分辨率进行表征。所有生产的样品都被发现具有从测试中检测到的高分辨率,即它们是透明的而不是半透明的。透射,反射率和吸收系数报告了不同的波长。发现吸收系数高度依赖于处理时间。退火实验帮助确定氧空位(有自由电子)是可见波长的主要吸收中心。此外,还发现晶界核或其相关缺陷对可见光范围内的光吸收没有显著贡献。从晶界空间电荷层中氧空位浓度低的角度讨论了晶界区域的影响不足。
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来源期刊
Optical Materials
Optical Materials 工程技术-材料科学:综合
CiteScore
6.60
自引率
12.80%
发文量
1265
审稿时长
38 days
期刊介绍: Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials. OPTICAL MATERIALS focuses on: • Optical Properties of Material Systems; • The Materials Aspects of Optical Phenomena; • The Materials Aspects of Devices and Applications. Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.
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