Spray pyrolisis deposition and characterization of Cd-TiO2 thin film for photocatalytic and photovoltaic applications

IF 2.9 Q2 ELECTROCHEMISTRY Journal of Electrochemical Science and Engineering Pub Date : 2022-08-03 DOI:10.5599/jese.1120
M. Rasekaran, P. Kumaresan, S. Nithiyanantham, Vatakkaputhanmadom Krishnaiyer Subramanian, Sankar Kalpana
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Abstract

In the present paper, an innovative approach to enhance the photocatalytic efficiency and energy of photovoltaics by modifying the surface morphology of TiO2 is demonstrated. The photovoltaic device provides sustainable power efficiency in TiO2 (TO) and Cd-TiO2 (CTO) thin films grown through spray pyrolysis. The structural and optical properties of the prepared undoped and Cd doped TiO2 thin films were studied. The morphology and content of the pro­duced samples were studied using scanning electron microscopy (SEM with EDAX). A UV-Vis spectrophotometer was used to record the optical absorption spectra of TiO2 nanoparticles. XRD analysis showed that TO and CTO had anatase structures, and the average crystalline size was calculated as 132.0 nm. The photocatalytic efficiency of TO and CTO for degradation of Rodhamine B (RhB) dye was examined. Also, power-voltage (P-V) and photocurrent-voltage (I-V) output current intensity relations were discussed.
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光催化和光伏应用中Cd-TiO2薄膜的喷雾热解沉积和表征
本文展示了一种通过改变TiO2表面形貌来提高光伏电池光催化效率和能量的创新方法。该光伏装置为通过喷雾热解生长的TiO2 (TO)和Cd-TiO2 (CTO)薄膜提供了可持续的电力效率。研究了制备的未掺杂和掺杂Cd的TiO2薄膜的结构和光学性能。用扫描电子显微镜(SEM with EDAX)研究了样品的形貌和含量。采用紫外可见分光光度计记录TiO2纳米粒子的光吸收光谱。XRD分析表明,TO和CTO具有锐钛矿结构,平均晶粒尺寸为132.0 nm。考察了TO和CTO光催化降解罗汉明B (RhB)染料的效率。并讨论了功率电压(P-V)和光电流电压(I-V)输出电流强度的关系。
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来源期刊
CiteScore
3.60
自引率
27.30%
发文量
90
审稿时长
6 weeks
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