TiO2/FetiO3/WO3 Ternary Composite Semiconductor as Efficient Photocatalyst: Structural Designing, Characteraization and Investigation of Photocatalytic Efficiency

Parvathy, Saranya, and Sivakumar
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引用次数: 3

Abstract

WO3, FeTiO3 and TiO2 photocatalyst prepared by simple sol-gel method followed by thermal treatment at 550°C, 550°C and 450°C for 3 hours respectively. TiO2/FeTiO3/ WO3 ternary composite has shown good activity for the degradation of reactive dyes in UVvisible light than that of binary composites such as TiO2/WO3, TiO2/FeTiO3. The prepared photocatalyst characterized by various techniques. 2 wt% TiO2/FeTiO3/WO3 ternary composite has demonstrated highest activity for the degradation of Reactive Blue 160 (RB 160). The composite photocatalyst also has good reusability; the 2 wt% TiO2/FeTiO3/WO3 photocatalyst completely degraded RB 160 in 120 minutes than that of parent photocatalysts. COD analysis of the degraded dye solution shows more than 70% of dye molecules in 100 mg l-1 reactive dye solution were mineralized in 3 hours. Hence, RB 160 photocatalyst will be an efficient and simplest method for the degradation of organic dyes and other organic pollutants in industrial effluent.
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TiO2/FetiO3/WO3三元复合半导体作为高效光催化剂:结构设计、表征及光催化效率研究
采用简单溶胶-凝胶法制备WO3、FeTiO3和TiO2光催化剂,分别在550℃、550℃和450℃下热处理3小时。TiO2/FeTiO3/ WO3三元复合材料在紫外可见光下对活性染料的降解活性优于TiO2/WO3、TiO2/FeTiO3二元复合材料。所制备的光催化剂经多种工艺表征。TiO2/FeTiO3/WO3三元复合材料对活性蓝160 (RB 160)的降解活性最高。复合光催化剂具有良好的可重复使用性;2 wt% TiO2/FeTiO3/WO3光催化剂比母光催化剂在120分钟内完全降解RB 160。降解染料溶液的COD分析表明,在100 mg l-1活性染料溶液中,3小时内70%以上的染料分子矿化。因此,rb160光催化剂将是一种高效、简单的降解工业废水中有机染料和其他有机污染物的方法。
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