Anion Colorimetric Chemosensor Based on a Benzimidazole-Functionalized BODIPY Derivative

ECSOC-25 Pub Date : 2022-07-18 DOI:10.3390/ecsoc-25-11754
R. Gonçalves, Sónia C. S. Pinto, S. Costa, M. Raposo
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引用次数: 3

Abstract

: A BODIPY derivative bearing a benzimidazole unit at position 2 and an electron donor group (anthracene) at the meso position was synthetized and characterized by the usual spectroscopic techniques. The evaluation of the compound as a colorimetric chemosensor was performed in solutions of acetonitrile/water (75:25) in the presence of several anions (HSO 4 − , NO 3 − , H 2 PO 4 − , CN − , BzO − , ClO 4 − , Br − , F − , I − and CH 3 CO 2 − ) with biomedical and environmental relevance. The investigated BODIPY derivative demonstrated a selective color change from pink to yellow upon interaction with a hydrogen sulfate anion (HSO 4 − ).
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基于苯并咪唑功能化BODIPY衍生物的阴离子比色化学传感器
合成了一种具有2位苯并咪唑和中间位给电子基团(蒽)的BODIPY衍生物,并用通常的光谱技术对其进行了表征。在具有生物医学和环境相关性的阴离子(hso4−、no3−、h2po4−、CN−、BzO−、clo4−、Br−、F−、I−和ch3co 2−)存在的乙腈/水(75:25)溶液中,对该化合物作为比色化学传感器进行了评价。所研究的BODIPY衍生物在与硫酸氢阴离子(hso4 -)相互作用时显示出从粉红色到黄色的选择性颜色变化。
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