E. Gomaa, M. Diab, Adel Z. El Sonbati, Hamed M Abuo Elnader, Gannat S. Abd Elraoof
{"title":"Solvation Parameters for The Interaction of HgCl2 with Valporic Acid (VaA) in KNO3 Using Silver Working Electrode (Cyclic Voltammetry)","authors":"E. Gomaa, M. Diab, Adel Z. El Sonbati, Hamed M Abuo Elnader, Gannat S. Abd Elraoof","doi":"10.26655/JMCHEMSCI.2019.3.1","DOIUrl":null,"url":null,"abstract":"Redox reaction mechanism in absence and presence of Valporic Acid (VaA) was Studied in cyclic voltammetry, we used a new silver electrode made from pure Silver piece jointed to Copper wire and isolated by heat shrink polymer to insure Complete isolation, during measurments. The Silver electrode was polished with Al2O3 in woolen piece, washed and used for the cyclic voltammetric Study. The stability constants and Gibbs free energies of Complex reactions between HgCl2 and Valproic acid (VaA) in 0.01 M KNO3 at 22˚C were evaluated and their results were discussed.","PeriodicalId":16365,"journal":{"name":"Journal of Medicinal and Chemical Sciences","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Medicinal and Chemical Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.26655/JMCHEMSCI.2019.3.1","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Redox reaction mechanism in absence and presence of Valporic Acid (VaA) was Studied in cyclic voltammetry, we used a new silver electrode made from pure Silver piece jointed to Copper wire and isolated by heat shrink polymer to insure Complete isolation, during measurments. The Silver electrode was polished with Al2O3 in woolen piece, washed and used for the cyclic voltammetric Study. The stability constants and Gibbs free energies of Complex reactions between HgCl2 and Valproic acid (VaA) in 0.01 M KNO3 at 22˚C were evaluated and their results were discussed.
在循环伏安法中研究了Valporic Acid (VaA)不存在和不存在时的氧化还原反应机理。在测量过程中,我们使用了一种由纯银片与铜线连接而成的新型银电极,并通过热缩聚合物隔离,以确保完全隔离。将银电极用Al2O3在羊毛片上抛光,洗涤后用于循环伏安研究。测定了HgCl2与丙戊酸(VaA)在22℃、0.01 M KNO3溶液中络合反应的稳定常数和吉布斯自由能,并对其结果进行了讨论。