Risk of Fire and Health Hazards Due to Organic Solvents in Chemical Laboratories

Soron Yamauchi, Shunsuke Aoki, M. Mizuno, T. Akitsu
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Abstract

This report comprehensively explores the risks of organic solvents as both fire and health hazards based on the results of “working environment measurements”, as specified in Japan’s safety and health laws. The results in 2018 and 2019 in our chemical laboratory determined that the lids of many waste solvent containers were open, which may potentially result in both fire and health hazards. When organic solvents volatilize to fill a laboratory, the vapor may be markedly harmful to human health. Although the conditions in our laboratory have improved by 2020, our laboratory mainly uses methanol and acetone, both of which are highly flammable and could ignite to cause a fire. It should be noted that vaporizing liquid organic solvents and other gases are not under the purview of the Fire Service Act on Hazardous Materials (in Japan), which is limited to condensed or liquid phases with ignition and explosive properties. In this context, herein, we summarized the health hazards and fire hazards of organic solvents (category 4), including methanol, acetone and N,N-dimethylformamide, by analyzing the results of working environment measurements in our laboratory over a period of several years. From the perspective of health and fire safety, it is imperative to focus on strategies to mitigate the risks of organic solvents in chemical laboratories. The correlation of both aspects is also discussed based on the results.
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化学实验室中有机溶剂的火灾风险和健康危害
本报告根据日本安全和健康法中具体规定的"工作环境测量"结果,全面探讨了有机溶剂的火灾和健康危害风险。我们化学实验室2018年和2019年的结果确定,许多废溶剂容器的盖子是打开的,这可能会导致火灾和健康危害。当有机溶剂挥发到充满实验室时,蒸气可能对人体健康有明显的危害。虽然到2020年,我们实验室的条件有所改善,但我们实验室主要使用甲醇和丙酮,这两种物质都是高度易燃的,容易引燃引起火灾。应该指出的是,汽化的液体有机溶剂和其他气体不属于《危险材料消防法》(日本)的管辖范围,该法仅限于具有点火和爆炸特性的凝聚态或液相。在此背景下,我们总结了有机溶剂(第4类)的健康危害和火灾危害,包括甲醇、丙酮和N,N-二甲基甲酰胺,通过分析我们实验室几年来的工作环境测量结果。从健康和消防安全的角度来看,必须关注减轻化学实验室有机溶剂风险的策略。并在此基础上讨论了两者的相关性。
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