Investigating oxidative stability of lithium-ion battery electrolytes using synthetic charge-discharge profile voltammetry

IF 5.4 Q2 CHEMISTRY, PHYSICAL Journal of Power Sources Advances Pub Date : 2021-10-01 DOI:10.1016/j.powera.2021.100071
Alma Mathew , Matthew J. Lacey , Daniel Brandell
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Abstract

Electrolytes are an integral part of any electrochemical energy storage systems, including batteries. Among the many properties which determine the applicability of a Li-ion battery electrolyte, electrochemical stability – and for high voltage electrodes, in particular anodic stability – is a key parameter to consider. Despite being simple and straightforward to employ, the conventional linear sweep voltammetry (LSV) technique often leads to an over-estimation of the oxidative stability. In this study, an alternative approach termed Synthetic Charge-discharge Profile Voltammetry (SCPV) is explored to investigate the oxidative electrolyte stability. We have found this to be a convenient method of quantifying the anodic stability of the electrolyte in a more practically representative manner, in which passivation kinetics and electrode potential changes at the electrode-electrolyte interface are more appropriately reproduced. The viability of this technique is explored with liquid electrolytes based on ether, carbonate, sulfone and carbonate-sulfone mixtures, all with lithium hexafluorophosphate (LiPF6) salt, tested for a potential profile equivalent to LiNi0.5Mn1.5O4 electrodes. The credibility of this technique is validated by correlations to the coulombic efficiencies of corresponding half-cells.

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利用合成充放电曲线伏安法研究锂离子电池电解质的氧化稳定性
电解质是包括电池在内的任何电化学储能系统的组成部分。在决定锂离子电池电解液适用性的众多特性中,电化学稳定性——以及高压电极,特别是阳极稳定性——是需要考虑的一个关键参数。传统的线性扫描伏安法(LSV)虽然简单易用,但往往会导致对氧化稳定性的过高估计。在这项研究中,一种替代方法被称为合成充放电曲线伏安法(SCPV)被探索来研究氧化电解质的稳定性。我们发现这是一种方便的方法,以一种更实际的代表性的方式量化电解质的阳极稳定性,其中钝化动力学和电极电位在电极-电解质界面的变化更适当地再现。该技术的可行性与基于乙醚、碳酸盐、砜和碳酸盐岩-砜混合物的液体电解质进行了探讨,所有液体电解质都含有六氟磷酸锂(LiPF6)盐,测试了相当于LiNi0.5Mn1.5O4电极的电位分布。通过与相应半电池的库仑效率的相关性验证了该技术的可靠性。
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来源期刊
CiteScore
9.10
自引率
0.00%
发文量
18
审稿时长
64 days
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