Physicochemical Impacts of Formation and Assembly of Quantum Dots Flowery Island of the (Sr-Cr-O) Semiconductor

B. Balboul, Moustafa Shaban A. Selim
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Abstract

Abstract In this paper, we fabricate a reactive self-assembled nanostructure of strontium chromium oxygen system (Sr-Cr-O). The ternary oxide SrCrO4 has been prepared as a QDs decorated superlattice. Course of formation as well as the obtained composition was analyzed by a combination of Thermogravimetry (TGA), X-ray diffraction (XRD), UV-vis diffuse reflectance spectra (DRS), scanning electron microscopy in association with EDX and high resolution transmission electron microscopy (TEM). The obtained nanostructure was determined to be composed of SrCrO4 as the major phase and SrCrO3/ SrO1.95 as the minor phases. Excitonic absorption signatures in optical spectroscopy confirmed that quantum confinement is preserved. The methodology involves a modified co-precipitation method. Moreover, excellent UV-visible-light photocatalytic performance was improved toward Methylene blue dye.
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(Sr-Cr-O)半导体量子点花岛形成与组装的物理化学影响
摘要本文制备了一种反应性自组装的锶铬氧体系纳米结构(Sr-Cr-O)。制备了具有量子点修饰超晶格的三元氧化物SrCrO4。采用热重(TGA)、x射线衍射(XRD)、紫外-可见漫反射光谱(DRS)、扫描电子显微镜(EDX)和高分辨率透射电子显微镜(TEM)等方法对其形成过程和组成进行了分析。结果表明,所制备的纳米结构以SrCrO4为主相,SrCrO3/ SrO1.95为辅相。光谱学中的激子吸收特征证实了量子约束的存在。该方法包括一种改进的共沉淀法。此外,还提高了亚甲基蓝染料的紫外-可见光光催化性能。
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