Synthesis of polyvinylpyrolidone copolymers in the presence of two-component initiation systems

O. Grytsenko, Ľ. Dulebová, N. Baran, B. Berezhnyy, P. Voloshkevych
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Abstract

The paper presents the results of the study of copolymerization of 2-hydroxyethylmethacrylate (HEMA) with polyvinylpyrrolidone (PVP) under the action of two-component initiation systems of iron (II) sulfate/radical type initiator. The influence of the nature of the radical initiator (In) in the FeSO4/In system on the behavior of the polymerization of HEMA/PVP compositions, structural parameters of the polymer matrix network and properties of hydrogels based on pHEMA-gr-PVP copolymers were established.
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双组份引发体系下聚乙烯醇吡啶酮共聚物的合成
本文介绍了在硫酸铁/自由基型引发剂双组份引发体系作用下,2-羟乙基甲基丙烯酸酯(HEMA)与聚乙烯吡罗烷酮(PVP)共聚的研究结果。研究了FeSO4/In体系中自由基引发剂(In)的性质对HEMA/PVP共聚物聚合行为、聚合物基体网络结构参数和pHEMA-gr-PVP共聚物水凝胶性能的影响。
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