Characterization of Composites Manufactured Through Reshaping of EoL Thermoplastic Polymers Reinforced with Recycled Carbon Fibers

A. Donatelli, M. Schioppa, F. Valentino, A. Scalone, F. De Pascalis, M. Nacucchi, F. Caretto
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Abstract

This article investigates if and at what extent a recycling process based on grinding, melting and re-shaping of recycled carbon fibers reinforced thermoplastic polymers (rCFRPs) can affect their physical, mechanical and thermal properties. The aim is to establish if they can be taken into consideration in the manufacturing of new composite materials in different sectors: automotive, marine, sporting goods, etc. Composites materials were submitted to the measurement of the fibers length they are composed of, and then analyzed by means of tensile and impact tests and a dynamic mechanical analysis (DMA). All the characterizations were performed to both initial and recycled composites and, in some cases, they were replied also after the intermediate accelerated aging. Characterization performed confirmed that, as expected, the recycling process affects the properties of the composites, but in different manners and to a different extent when different polymers are involved. Tensile and impact tests pointed out that the polypropylene based composites showed a less stiff and a more brittle behaviour after the recycling process and the DMA confirmed this evidence, highlighting in addition a more viscous behavior of the polymer after the recycling. Conversely, the polyamide 6 based composites increased their stiffness and ductility after the recycling. For all the composites the tensile strength dropped, confirming the weakening of the materials.
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再生碳纤维增强EoL热塑性聚合物整形制备复合材料的研究
本文研究了基于磨削、熔融和再成型的再生碳纤维增强热塑性聚合物(rcfrp)的回收过程是否以及在多大程度上影响其物理、机械和热性能。目的是确定在汽车、船舶、体育用品等不同领域的新复合材料制造中是否可以考虑到它们。对复合材料进行纤维长度测量,并通过拉伸、冲击试验和动态力学分析(DMA)对其进行分析。所有的表征都是对初始复合材料和回收复合材料进行的,在某些情况下,它们在中间加速老化后也得到了回复。所进行的表征证实,正如预期的那样,回收过程影响复合材料的性能,但当涉及不同的聚合物时,其方式和程度不同。拉伸和冲击试验指出,聚丙烯基复合材料在回收处理后表现出较低的刚性和较脆的行为,DMA证实了这一证据,并强调了聚合物在回收后的粘性行为。相反,聚酰胺6基复合材料在循环利用后,其刚度和延展性有所提高。所有复合材料的抗拉强度均下降,证实了材料的弱化。
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