Epoxy composite with hBN fillers compatible with industrial application in electrical equipment

S. Haller, Damien Bachellerie, S. Pruvost, Loriane Desmars, S. Iglesias, J. Galy, G. Robert, Christian Lao, A. Girodet, M. Henriksen
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Abstract

Hexagonal Boron Nitride (hBN) has been used as secondary filler in an epoxy formulation in gas insulated substation (GIS) demonstrating higher electrical performance under HVAC stress, while being compatible with industrial process and constraints. A synergetic effect between hBN and alumina has been observed regarding thermal and electrical properties. A 500% increase in the thermal conductivity could be achieved with a limited impact on viscosity increase. Breakdown strength has been measured in flat sheets in oil and with embedded electrodes under divergent field simulating a defect. The breakdown strengths resulting from these different experimental setups show an interesting barrier effect from hBN even at low ratio in the formulation. Both results can be correlated with increased lifetime under thermoelectrical stress.
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环氧复合材料与hBN填料兼容的工业应用在电气设备
六方氮化硼(hBN)已被用作气体绝缘变电站(GIS)环氧树脂配方的二次填料,在暖通空调应力下具有更高的电气性能,同时与工业过程和约束相兼容。hBN和氧化铝在热学和电学性能方面具有协同效应。在对粘度增加影响有限的情况下,热导率可以增加500%。在模拟缺陷的发散场下,测量了油中的平板和嵌入电极的击穿强度。从这些不同的实验装置得到的击穿强度表明,即使在配方中的低比例下,hBN也有有趣的势垒效应。这两个结果都与热电应力下寿命的增加有关。
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