PHASE RELATIONS IN THE Sb2Te2S-Bi2Te2S SYSTEM AND CHARACTERIZATION OF Sb2-xBixTe2S SOLID SOLUTIONS

F.R. Aliyev, E. Orujlu, D. Babanly, A.L. Mustafayeva
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Abstract

The phase equilibria of the Sb2Te2S-Bi2Te2S system was studied by powder X-ray diffraction (PXRD), differential thermal analysis (DTA), scanning electron microscope (SEM) and energy dispersive Xray (EDX) microanalysis. It was shown that due to incongruent melting of the Sb2Te2S compound the system is non-quasibinary, but it is stable below the solidus and characterized by the formation of a continuous series of solid solutions with a tetradymite-like hexagonal structure. The lattice parameters were determined from powder diffraction patterns. It was established that the crystal lattice parameters of solid solutions vary linearly with composition
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Sb2Te2S-Bi2Te2S体系的相关系及Sb2-xBixTe2S固溶体的表征
采用粉末x射线衍射(PXRD)、差热分析(DTA)、扫描电镜(SEM)和能量色散x射线(EDX)分析研究了Sb2Te2S-Bi2Te2S体系的相平衡。结果表明,由于Sb2Te2S化合物的不一致熔化,该体系是非准二元的,但在固相以下稳定,并以形成一系列连续的固溶体为特征,具有类似四白石的六边形结构。根据粉末衍射图确定了晶格参数。确定了固溶体的晶格参数随组成呈线性变化
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