Effect of adding hygroscopic salts on the analysis of the volatile fraction of cheese

Analusis Pub Date : 2000-12-01 DOI:10.1051/ANALUSIS:2000164
D. Canac-Arteaga, F. Begnaud, C. Viallon, J. Berdagué
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引用次数: 6

Abstract

We investigated the effect of adding hygroscopic salts on the analysis by dynamic headspace - gas chromatography - mass spectrometry of the volatile fraction of cheese. We tested five salts: calcium chloride, magnesium sulfate, potassium car- bonate, sodium chloride and sodium sulfate. Relative humidity of the headspace, pH value of the matrix, desorption of volatile components and their odor were modified differently according to the salt used. Adding magnesium sulfate or potassium car- bonate respectively released carboxylic acids and amino compounds from the matrix, whereas calcium chloride restricted the over- all desorption of the volatile components. Sodium sulfate and sodium chloride had little effect.
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加入吸湿盐对奶酪挥发分分析的影响
研究了添加吸湿盐对动态顶空-气相色谱-质谱法分析干酪挥发分的影响。我们测试了五种盐:氯化钙、硫酸镁、碳酸钾、氯化钠和硫酸钠。顶空相对湿度、基质pH值、挥发性组分的解吸及其气味根据所用盐的不同而有不同的改变。添加硫酸镁和碳酸钾分别释放基质中的羧酸和氨基化合物,而添加氯化钙则限制了挥发性组分的全面解吸。硫酸钠和氯化钠作用不大。
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