{"title":"Synthesis and characterization of poly p-PDA/SnO2 nanocomposites using chloro (glycinato)-(1, 10-phenanthroline) copper (II) monohydrate complex","authors":"Bharat Nayak, S. Baruah, A. Puzari","doi":"10.1063/5.0061164","DOIUrl":null,"url":null,"abstract":"A series of poly p-PDA/SnO2 nanocomposites with different p-PDA: SnO2 ratios were prepared by ‘in-situ’ deposition oxidative polymerization of paraphenylenediammine hydrochloride using Hydrogen peroxide (H2O2) as oxidant.Our main focus of the work was to use chloro (glycinato)-(1, 10-phenanthroline) copper (II) monohydrate complex as a catalyst to improve the yield of the reaction and results were quite promising. Physicochemical characterization was done using spectroscopic techniques such as FT-IR, XRD, TGA, SEM and I-V techniques. XRD results are indicative of the crystalline structure with long-range ordering of the nanocomposies.TGA results confirms the increase in the thermal stability due to the incorporation of SnO2 nanoparticles. Conductivity values obtained from I-V measurements, confirms the suitability of the nanocomposites for the use in the field of optoelectronics.","PeriodicalId":18837,"journal":{"name":"NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020","volume":"18 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM2020","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/5.0061164","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A series of poly p-PDA/SnO2 nanocomposites with different p-PDA: SnO2 ratios were prepared by ‘in-situ’ deposition oxidative polymerization of paraphenylenediammine hydrochloride using Hydrogen peroxide (H2O2) as oxidant.Our main focus of the work was to use chloro (glycinato)-(1, 10-phenanthroline) copper (II) monohydrate complex as a catalyst to improve the yield of the reaction and results were quite promising. Physicochemical characterization was done using spectroscopic techniques such as FT-IR, XRD, TGA, SEM and I-V techniques. XRD results are indicative of the crystalline structure with long-range ordering of the nanocomposies.TGA results confirms the increase in the thermal stability due to the incorporation of SnO2 nanoparticles. Conductivity values obtained from I-V measurements, confirms the suitability of the nanocomposites for the use in the field of optoelectronics.