Effect of Catalyst Type on the Properties of Biodiesel from Jathropha and Moringa Oil Blend

I. Bamgboye, B. N. Iyidiobu
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Abstract

Various methods of biodiesel production have been developed in the recent past to reduce production costs. These new approaches may have varying effects on ester quality. Thus an investigation is necessary to determine cost saving measures that do not compromise ester quality. This work examined the effects of a cost saving strategy on Biodiesel quality. This conservative method involved the transesterification of a Jathropha-Moringa oil blend using a blend of two primary alcohols. Three alkaline catalysts were also used. The reaction conditions were: Jathropha to Moringa oil blending ratio of 4:1; Methanol to ethanol blending ratio of 4:1; Alkaline catalyst concentration of 0.5 w/w %; reaction time of 40 minutes; stirring speed of 1000 rpm; Temperature of 60°C and an Alcohol to oil molar ratio of 7.5. Biodiesel samples were tested according to ASTM D6751 and AOCS guidelines. Results indicated that the density, iodine values, flash point and fire points of esters did not vary significantly as the experiment was repeated using three different alkaline catalysts. It also showed that the effect of NaOH, KOH and CaO were not always negative when they were significant. Lastly, the methods applied in this did not compromise ester quality with regard to observed fuel parameters.
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催化剂类型对麻疯树与辣木油混合制备生物柴油性能的影响
为了降低生产成本,近年来开发了各种生物柴油的生产方法。这些新方法可能对酯的质量产生不同的影响。因此,有必要进行调查,以确定不影响酯质量的成本节约措施。本研究考察了成本节约策略对生物柴油质量的影响。这种保守的方法包括用两种伯醇的混合物对麻辣木油进行酯交换反应。还使用了三种碱性催化剂。反应条件为:麻疯树与辣木油的配比为4:1;甲醇与乙醇混合比例为4:1;碱性催化剂浓度为0.5 w/w %;反应时间40分钟;搅拌速度1000转/分;温度为60℃,醇油摩尔比为7.5。生物柴油样品根据ASTM D6751和AOCS指南进行测试。结果表明,三种不同碱性催化剂对酯类的密度、碘值、闪点和燃点均无显著影响。NaOH, KOH和CaO的影响并不总是负的,当它们显著时。最后,在此应用的方法不损害酯质量有关观察到的燃料参数。
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