The effect of anions on decolorization of textile azo dye Reactive Orange 16 with UV/H2O2 process

Abstract

The effects of various organic and inorganic anions on decolorization of textile dye Reactive Orange 16 by means of hydroxyl radicals have been studied. These anions are commonly present in wastewaters from textile industry and include chloride, sulfate, carbonate/bicarbonate, nitrate and acetate anions. The experiments were conducted in the presence of different concentrations of anions and at different initial pH values in a batch photoreactor equipped with UV-C (254 nm) lamps in the presence of hydrogen peroxide. It was obtained that decolorization efficiency was significantly affected by nature and concentration of the investigated anions. An inhibitory effect of acetate anions increased with increasing in their concentration and depended on whether protonated or deprotonated forms are favored. Carbonate anion showed specific, both positive and negative influence, depending on its concentration. Influence of bicarbonate, nitrate and chloride was more prominent at their higher initial concentrations. The presence of sulfate did not have noticeable impact on decolorization of RO16 dye under investigated conditions.