ACYLATION OF THE ANHYDRITE-CONTAINING COPOLYMERS WITH VINYL CARBINOL FOR PREPARATION OF PHOTOSENSITIVE MATERIALS

F.Kh. Yusifli, T. Guliyev, G. Ramazanov
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Abstract

By copolymerization of cycloalkyl-substituted methylenedioxolanes with maleic anhydride the copolymers, which were subjected to acylation reactions with vinyl carbinol were obtained. It was revealed that as a result of the reaction, the copolymers with various degrees of etherification were obtainedIt found that the obtained etherified copolymers exhibited various UV sensitivity depending on the degree of etherification. It revealed that the availability of highly absorbing fragments such as allyl and carbonyl groups in macromolecules of the etherified copolymers provides these polymers, along with high light-sensitivity, with film-forming properties and good adhesion to quartz substrate.
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含硬石膏共聚物与乙烯基甲醇的酰化制备光敏材料
由环烷基取代的亚甲基二氧索烷与马来酸酐共聚,得到了与甲醇酰化反应的共聚物。结果表明,通过该反应可以得到不同醚化程度的共聚物,并发现所得到的醚化共聚物对紫外光的敏感性随醚化程度的不同而不同。结果表明,醚化共聚物大分子中烯丙基和羰基等高吸收片段的可用性,使这些聚合物具有高光敏性,具有成膜性能和与石英衬底的良好粘附性。
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