Silver Doping Effects on ZnTe Thin Films by Thermal Evaporation Technique

N. Shah, Syed Aa, A. Murrawat
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引用次数: 3

Abstract

Zinc telluride (ZnTe) thin films were fabricated by thermal evaporation method on corning glass substrates. ZnTe thin films were doped with silver (Ag) by dipping in low concentrated solution (0.2 g/200 ml) of AgNO3 × H2O at room temperature. X-ray diffraction technique was used to investigate the structural behavior of ZnTe samples. Optical investigations were done by using spectrophotometer. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) were used to analyze the surface and composition of the thin film samples respectively. Electrical investigations were done by using Van Der Pauw and Hall measurement system. It was found that prepared samples showed polycrystalline structure with as preferred orientation. Optical study showed that with increasing thickness, grain size increased but optical transmission and energy band gap were decreased. It was observed that value of resistivity of these samples decreased with increasing thickness and Ag composition. The results were compared before and after Ag doping in ZnTe thin films samples for the solar cell applications.
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热蒸发技术对ZnTe薄膜银掺杂的影响
采用热蒸发法制备了碲化锌(ZnTe)薄膜。在室温下,将银(Ag)掺杂于AgNO3 × H2O低浓溶液(0.2 g/200 ml)中。采用x射线衍射技术研究了ZnTe样品的结构行为。用分光光度计进行光学研究。利用扫描电镜(SEM)和能量色散x射线能谱(EDX)分别分析了薄膜样品的表面和成分。电学测量采用范德保和霍尔测量系统。结果表明,制备的样品具有相同择优取向的多晶结构。光学研究表明,随着厚度的增加,晶粒尺寸增大,但光透射率和能带间隙减小。观察到试样的电阻率随厚度和银含量的增加而减小。比较了太阳能电池用ZnTe薄膜样品中Ag掺杂前后的结果。
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