An Integrated Approach to Produced Water Treatment using Sand Filtration, Activated Carbon and Microemulsions modified Activated Carbon

M. Al-Kaabi, M. Al‐Ghouti, N. Zouari, T. Ahmed
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Abstract

The produced water from natural gas production process in the North field offshore is considered as the largest wastewater volume in Qatar, which could be potentially used for clean water resources for the industry as well as for some other domestic uses, if it is treated properly. This research aims to study the physical and chemical characterizations of the produced water from the North field and examine the removal of major inorganic and organic pollutants and heavy metals from the PW by using different treatments method such as using the sand filtration, activated carbon filtration and modified activated carbon filtration. The physical and chemical characterization of produced water was examined followed by treatment through sand filtration coupled with activated carbon and microemulsion modified activated carbon techniques. The results of characterization showed that the produced water had high concentration of COD, TOC, BTEX and various metals. After sand filtration, considerable reduction in TSS and COD was achieved. Furthermore, BTEX were also removed by more than 93% except for toluene. However, sand filtration was not enough to remove most of the metals and ions. Therefore, further treatment was done through activated carbon and modified activated carbon and their treatment efficiency was compared. Both techniques were able to achieve higher removal efficiencies for BTEX, metals and ions. Thus, the treated water was free from all major pollutants of PW and can be considered suitable for reuse at industrial application. Further studies and applications could be applied on produced water such as studying the biological characterization and applying biological treatment processes.
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砂滤、活性炭及微乳液改性活性炭综合处理采出水的研究
北海油田天然气生产过程中的产出水被认为是卡塔尔最大的废水量,如果处理得当,这些废水可能会被用于该行业的清洁水资源以及其他一些家庭用途。本研究旨在研究北方油田采出水的理化特性,考察砂过滤、活性炭过滤和改性活性炭过滤等不同处理方法对污水中主要无机、有机污染物和重金属的去除效果。研究了采出水的物理和化学特性,然后采用砂滤结合活性炭和微乳液改性活性炭技术进行处理。表征结果表明,采出水中COD、TOC、BTEX及多种金属含量较高。砂滤后,TSS和COD显著降低。除甲苯外,BTEX的去除率均在93%以上。然而,砂过滤不足以去除大部分金属和离子。因此,对活性炭和改性活性炭进行了进一步处理,并比较了它们的处理效果。这两种技术都能够实现更高的BTEX、金属和离子的去除效率。因此,处理后的水不含PW的所有主要污染物,可以认为适合在工业应用中重复使用。在采出水的生物特性研究、生物处理工艺的应用等方面,可进行进一步的研究和应用。
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