A multi-reflection time-of-flight mass spectrometer for the offline ion source of the PUMA experiment

IF 1.6 3区 化学 Q3 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL International Journal of Mass Spectrometry Pub Date : 2023-10-31 DOI:10.1016/j.ijms.2023.117166
M. Schlaich , J. Fischer , P. Fischer , C. Klink , A. Obertelli , A. Schmidt , L. Schweikhard , F. Wienholtz
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Abstract

The antiProton Unstable Matter Annihilation experiment (PUMA) at CERN aims at investigating the nucleon composition in the matter density tail of radioactive as well as stable isotopes by use of low-energy antiproton-nucleon annihilation processes. For this purpose, antiprotons provided by the Extra Low ENergy Antiproton (ELENA) facility will be trapped together with the ions of interest. While exotic ions will be obtained by the Isotope mass Separator On-Line DEvice (ISOLDE), stable ions will be delivered from an offline ion source setup designed for this purpose. This allows the proposed technique to be applied to a variety of stable nuclei and for reference measurements. For beam purification, the ion source setup includes a multi-reflection time-of-flight mass spectrometer (MR-ToF MS). Supported by SIMION® simulations, an earlier MR-ToF MS design has been modified to meet the requirements of PUMA. During commissioning of the new MR-ToF device with Ar+ ions, mass resolving powers in excess of 50,000 have been obtained after 150 revolutions, limited by the chopping of the continuous beam from an electron impact ionisation source.

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用于PUMA实验脱机离子源的多反射飞行时间质谱仪
欧洲核子研究中心的反质子不稳定物质湮灭实验(PUMA)旨在利用低能反质子-核子湮灭过程研究放射性和稳定同位素物质密度尾的核子组成。为此,超低能反质子(ELENA)设备提供的反质子将与感兴趣的离子一起被捕获。外来离子将由同位素质量分离器在线设备(ISOLDE)获得,稳定离子将由为此目的设计的离线离子源装置提供。这使得所提出的技术可以应用于各种稳定的原子核和参考测量。对于光束净化,离子源装置包括一个多反射飞行时间质谱仪(MR-ToF MS)。在SIMION®仿真的支持下,早期的MR-ToF MS设计已经过修改,以满足PUMA的要求。在使用Ar+离子的新型MR-ToF设备调试期间,由于受到来自电子冲击电离源的连续光束切割的限制,在150转后获得了超过50,000的质量分辨能力。
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来源期刊
CiteScore
3.60
自引率
5.60%
发文量
145
审稿时长
71 days
期刊介绍: The journal invites papers that advance the field of mass spectrometry by exploring fundamental aspects of ion processes using both the experimental and theoretical approaches, developing new instrumentation and experimental strategies for chemical analysis using mass spectrometry, developing new computational strategies for data interpretation and integration, reporting new applications of mass spectrometry and hyphenated techniques in biology, chemistry, geology, and physics. Papers, in which standard mass spectrometry techniques are used for analysis will not be considered. IJMS publishes full-length articles, short communications, reviews, and feature articles including young scientist features.
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