Nanocrystalline α-Fe2O3: A superparamagnetic material for w-LED application and waste water treatment

IF 2.218 Q2 Chemistry Chemical Data Collections Pub Date : 2023-10-01 DOI:10.1016/j.cdc.2023.101083
Mahesh Gaidhane , Deepak Taikar , Pravin Gaidhane , Kalpana Nagde
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Abstract

Nanocrystalline α-Fe2O3 was synthesized by sol-gel technique and then characterized by X-ray diffraction (XRD), SEM, TEM, Fourier Transform Infrared (FTIR) spectroscopy, Vibrating Sample Magnetometry (VSM), and photoluminescence (PL) techniques. The X-ray powder diffraction analysis confirmed the formation of α-Fe2O3. Electron microscopy showed spherical morphologies with an average particle size of 30–40 nm. VSM study shows superparamagnetic nature of the synthesized nanoparticles. Furthermore, PL emission spectra showed an intense broad emission band centered at 570 nm with 393 nm excitation, indicating that it can be used for w-LED application. The CIE-chromaticity color coordinates of prepared material were calculated. The photocatalytic activity of the α-Fe2O3 nanoparticles was analyzed, which exhibited good photocatalytic activity for the removal AO7 from its aqueous solution.

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纳米晶α-Fe2O3:用于w-LED应用和废水处理的超顺磁性材料
采用溶胶-凝胶法制备了α-Fe2O3纳米晶,并用x射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、傅里叶变换红外光谱(FTIR)、振动样品磁强学(VSM)和光致发光(PL)技术对其进行了表征。x射线粉末衍射分析证实了α-Fe2O3的形成。电镜显示为球形,平均粒径为30-40 nm。VSM研究表明合成的纳米颗粒具有超顺磁性。此外,在393 nm激发下,PL发射光谱显示出以570 nm为中心的强宽发射带,表明该材料可用于w-LED。计算了所制备材料的cie -色度色坐标。对α-Fe2O3纳米粒子的光催化活性进行了分析,结果表明α-Fe2O3纳米粒子对水溶液中的AO7具有良好的光催化活性。
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Chemical Data Collections
Chemical Data Collections Chemistry-Chemistry (all)
CiteScore
6.10
自引率
0.00%
发文量
169
审稿时长
24 days
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