Molecular association studies through physicochemical properties and application of Prigogine-Flory-Patterson theory to binary liquid mixtures of furfuryl alcohol with acetophenone, cyclopentanone and cyclohexanone

IF 2.218 Q2 Chemistry Chemical Data Collections Pub Date : 2023-10-02 DOI:10.1016/j.cdc.2023.101091

K.A. Sasikala , K. Rayapa Reddy , M. Silpa , P.V.S. Sairam , G. Srinivasa Rao

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Abstract

Speed of ultrasound (U), density (ρ) of pure and binary mixtures of furfuryl alcohol with three ketones, viz., acetophenone, cyclopentanone and cyclohexanone have been measured at temperatures 303.15 K - 318.15 K (∆T = 5 K), at atmospheric pressure. Excess/deviation parameters namely, excess intermolecular free length ( $L_{f}^{E}$ ), excess volume per mole ( $V_{m}^{E}$ ) and deviation in isentropic compressibility (∆κ_s) have been determined from the experimental data. Redlich-Kister polynomial equation has been considered for the fitting parameters of excess functions and the standard deviation is estimated. The results of excess properties are supported by partial volume per mole studies. To endorse the thermodynamic results, Prigogine–Flory–Patterson theory has been applied for excess molar volumes.

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呋喃醇与苯乙酮、环戊酮和环己酮二元液体混合物的理化性质及其应用

在303.15 K - 318.15 K(∆T = 5k)和常压下，测量了糠醇与三种酮即苯乙酮、环戊酮和环己酮的纯混合物和二元混合物的超声速度(U)和密度(ρ)。根据实验数据确定了过量/偏差参数，即过量分子间自由长度(LfE)、每摩尔过量体积(VmE)和等熵压缩偏差(∆κs)。采用Redlich-Kister多项式方程拟合多余函数的参数，并估计了标准差。过量性质的结果得到了每摩尔部分体积研究的支持。为了支持热力学结果，将Prigogine-Flory-Patterson理论应用于过量摩尔体积。

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来源期刊

Chemical Data Collections Chemistry-Chemistry (all)

CiteScore

6.10

自引率

0.00%

发文量

169

审稿时长

24 days

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