Polytypism of Ln(SeO3)(HSeO3)·2H2O compounds: synthesis and crystal structure of the first monoclinic modification of Nd(SeO3)(HSeO3)·2H2O, DFT calculations and order/disorder description.

Abstract

Compounds with the general formula Ln³⁺(SeO₃)(HSeO₃)·2H₂O, where Ln = Sm³⁺, Tb³⁺, Nd³⁺ and Lu³⁺, are characterized by orthorhombic symmetry with space group P2₁2₁2₁ and unit-cell parameters in the ranges a ∼ 6.473-6.999, b ∼ 6.845-7.101, c ∼ 16.242-16.426 Å. Light-purple irregularly shaped crystals of a new monoclinic polytype of neodymium selenite Nd(SeO₃)(HSeO₃)·2H₂O have been obtained during a mild-condition hydrothermal synthesis. The monoclinic unit-cell parameters are: a = 7.0815 (2), b = 6.6996 (2), c = 16.7734 (5) Å, β = 101.256 (1)°, V = 780.48 (6) ų; space group P2₁/c. The crystal structures of Nd(SeO₃)(HSeO₃)·2H₂O polymorphs show order-disorder (OD) character and can be described using the same OD groupoid family, more precisely a family of OD structures built up from two kinds of non-polar layers (category IV). The first monoclinic maximum degree order (MDO) structure (MDO1-polytype) with space group P2₁/c can be obtained when the inversion centre is active in the L_2n-type layers, while the second MDO structure (MDO2-polytype) is orthorhombic with space group P2₁2₁2₁ and can be obtained when the [2₁--] operation is active in the L_2n-type layers. The structural complexity parameters and DFT calculations of both polytypes show that the polytype structures are extremely close energy-wise and almost equally viable from the point of total energy of the structure.