Structural characteristics and thermal performances of lauric-myristic-palmitic acid introduced into modified water hyacinth porous biochar for thermal energy storage.
{"title":"Structural characteristics and thermal performances of lauric-myristic-palmitic acid introduced into modified water hyacinth porous biochar for thermal energy storage.","authors":"Jiahong Zhou, Hua Fei, Qian He, Peisheng Li, Yucheng Pan, Ximei Liang","doi":"10.1016/j.scitotenv.2023.163670","DOIUrl":null,"url":null,"abstract":"<p><p>Water hyacinth (WH) was used to prepare biochar for phase change energy storage field to realize encapsulation and enhance thermal conductivity of phase change materials (PCMs) in this work. The maximum specific surface area of modified water hyacinth biochar (MWB) obtained by lyophilization and carbonization at 900 °C was 479.966 m<sup>2</sup>/g. Lauric-myristic-palmitic acid (LMPA) was used as phase change energy storage material, LWB900 and VWB900 were used as porous carriers respectively. Modified water hyacinth biochar matrix composite phase change energy storage materials (MWB@CPCMs) were prepared by vacuum adsorption method, with loading rates of 80 % and 70 % respectively. The enthalpy of LMPA/LWB900 was 105.16 J/g, which was 25.79 % higher than that of LMPA/VWB900, and the energy storage efficiency was 99.1 %. Moreover, the introduction of LWB900 increased the thermal conductivity (k) of LMPA from 0.2528 W/(m·K) to 0.3574 W/(m·K). MWB@CPCMs have good temperature control capability, and the heating time of LMPA/LWB900 was 15.03 % higher than that of LMPA/VWB900. In addition, after 500 thermal cycles, the maximum change rate of enthalpy of LMPA/LWB900 was 6.56 %, and it maintains a phase change peak, showing better durability than LMPA/VWB900. This study shows that the preparation process of LWB900 is the best, and the adsorption of LMPA has high enthalpy value and stable thermal performance, realizing the sustainable development of biochar.</p>","PeriodicalId":422,"journal":{"name":"Science of the Total Environment","volume":null,"pages":null},"PeriodicalIF":8.2000,"publicationDate":"2023-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science of the Total Environment","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.scitotenv.2023.163670","RegionNum":1,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 2
Abstract
Water hyacinth (WH) was used to prepare biochar for phase change energy storage field to realize encapsulation and enhance thermal conductivity of phase change materials (PCMs) in this work. The maximum specific surface area of modified water hyacinth biochar (MWB) obtained by lyophilization and carbonization at 900 °C was 479.966 m2/g. Lauric-myristic-palmitic acid (LMPA) was used as phase change energy storage material, LWB900 and VWB900 were used as porous carriers respectively. Modified water hyacinth biochar matrix composite phase change energy storage materials (MWB@CPCMs) were prepared by vacuum adsorption method, with loading rates of 80 % and 70 % respectively. The enthalpy of LMPA/LWB900 was 105.16 J/g, which was 25.79 % higher than that of LMPA/VWB900, and the energy storage efficiency was 99.1 %. Moreover, the introduction of LWB900 increased the thermal conductivity (k) of LMPA from 0.2528 W/(m·K) to 0.3574 W/(m·K). MWB@CPCMs have good temperature control capability, and the heating time of LMPA/LWB900 was 15.03 % higher than that of LMPA/VWB900. In addition, after 500 thermal cycles, the maximum change rate of enthalpy of LMPA/LWB900 was 6.56 %, and it maintains a phase change peak, showing better durability than LMPA/VWB900. This study shows that the preparation process of LWB900 is the best, and the adsorption of LMPA has high enthalpy value and stable thermal performance, realizing the sustainable development of biochar.
期刊介绍:
The Science of the Total Environment is an international journal dedicated to scientific research on the environment and its interaction with humanity. It covers a wide range of disciplines and seeks to publish innovative, hypothesis-driven, and impactful research that explores the entire environment, including the atmosphere, lithosphere, hydrosphere, biosphere, and anthroposphere.
The journal's updated Aims & Scope emphasizes the importance of interdisciplinary environmental research with broad impact. Priority is given to studies that advance fundamental understanding and explore the interconnectedness of multiple environmental spheres. Field studies are preferred, while laboratory experiments must demonstrate significant methodological advancements or mechanistic insights with direct relevance to the environment.