水性钠离子电池用锰基电极材料的研究进展。

IF 31.6 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Nano-Micro Letters Pub Date : 2023-08-09 DOI:10.1007/s40820-023-01162-x

Changsheng Ding, Zhang Chen, Chuanxiang Cao, Yu Liu, Yanfeng Gao

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引用次数: 0

摘要

水性钠离子电池由于其丰富的钠资源、低成本、水性电解质的本质安全性和生态友好性，在大规模储能应用中引起了广泛关注。水性钠离子电池的电化学性能受电极材料和电解质性能的影响。在各种电极材料中，Mn基电极材料以其丰富的Mn、低成本、无毒、环保和有趣的电化学性能而备受关注。具有窄电化学窗口的水性电解质也影响Mn基电极材料的电化学性能。在这篇综述中，我们从阴极材料和阳极材料两个方面系统地介绍了用于水性钠离子电池的锰基电极材料，并对其最新发展进行了全面的概述。这些Mn基材料包括氧化物、普鲁士蓝类似物和聚阴离子化合物。综述和讨论了锰基电极材料的组成、晶体结构、形貌和电化学性能。重点介绍了基于电解质优化、元素掺杂或取代、形貌优化和碳改性的改进方法。并对锰基电极材料的发展前景进行了展望。我们认为这篇综述对探索和应用锰基电极材料在水性钠离子电池中具有重要意义。

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Advances in Mn-Based Electrode Materials for Aqueous Sodium-Ion Batteries

Highlights

Mn-based electrode materials, including oxides, Prussian blue analogues and polyanion compounds, are introduced systematically for aqueous sodium-ion batteries.
The composition, crystal structure, morphology and electrochemical performance of Mn-based electrode materials are reviewed.
The improvement methods of electrochemical performance, such as electrolyte optimization, element doping or substitution, morphology optimization and carbon modification, are discussed.

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来源期刊

Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

42.40

自引率

4.90%

发文量

715

审稿时长

13 weeks

期刊介绍： Nano-Micro Letters is a peer-reviewed, international, interdisciplinary and open-access journal that focus on science, experiments, engineering, technologies and applications of nano- or microscale structure and system in physics, chemistry, biology, material science, pharmacy and their expanding interfaces with at least one dimension ranging from a few sub-nanometers to a few hundreds of micrometers. Especially, emphasize the bottom-up approach in the length scale from nano to micro since the key for nanotechnology to reach industrial applications is to assemble, to modify, and to control nanostructure in micro scale. The aim is to provide a publishing platform crossing the boundaries, from nano to micro, and from science to technologies.