{"title":"用LIF检测NO3自由基与1-丁烯、反式丁烯、2-甲基-2-丁烯和2,3-二甲基-2-丁烯气相反应动力学","authors":"T. Berndt, I. Kind, H.-J. Karbach","doi":"10.1002/bbpc.199800017","DOIUrl":null,"url":null,"abstract":"<p>Rate constants for the gas-phase reaction of NO<sub>3</sub> radicals with 1-butene, <i>trans</i>-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298±2 K and a pressure of 3 mbar He using NO<sub>3</sub> LIF measurements. NO<sub>3</sub> radicals were produced via thermal decomposition of N<sub>2</sub>O<sub>5</sub> at ca. 400 K, i.e. N<sub>2</sub>O<sub>5</sub>+M → NO<sub>3</sub>+NO<sub>2</sub>+M.</p><p>Applying pseudo-first-order conditions, the rate constants for 1-butene and <i>trans</i>-butene were found to be (1.04±0.11)·10<sup>−14</sup> and (3.74±0.45)·10<sup>−13</sup>, respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03±0.09)·10<sup>−11</sup> and (5.49±0.42)·10<sup>−11</sup>, respectively (unit: cm<sup>3</sup> molecule<sup>−1</sup> s<sup>1</sup>).</p>","PeriodicalId":100156,"journal":{"name":"Berichte der Bunsengesellschaft für physikalische Chemie","volume":"102 10","pages":"1486-1491"},"PeriodicalIF":0.0000,"publicationDate":"2014-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/bbpc.199800017","citationCount":"10","resultStr":"{\"title\":\"Kinetics of the Gas-Phase Reaction of NO3 Radicals with 1-Butene, trans-Butene, 2-Methyl-2-butene and 2,3-Dimethyl-2-butene Using LIF Detection\",\"authors\":\"T. Berndt, I. Kind, H.-J. Karbach\",\"doi\":\"10.1002/bbpc.199800017\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Rate constants for the gas-phase reaction of NO<sub>3</sub> radicals with 1-butene, <i>trans</i>-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298±2 K and a pressure of 3 mbar He using NO<sub>3</sub> LIF measurements. NO<sub>3</sub> radicals were produced via thermal decomposition of N<sub>2</sub>O<sub>5</sub> at ca. 400 K, i.e. N<sub>2</sub>O<sub>5</sub>+M → NO<sub>3</sub>+NO<sub>2</sub>+M.</p><p>Applying pseudo-first-order conditions, the rate constants for 1-butene and <i>trans</i>-butene were found to be (1.04±0.11)·10<sup>−14</sup> and (3.74±0.45)·10<sup>−13</sup>, respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03±0.09)·10<sup>−11</sup> and (5.49±0.42)·10<sup>−11</sup>, respectively (unit: cm<sup>3</sup> molecule<sup>−1</sup> s<sup>1</sup>).</p>\",\"PeriodicalId\":100156,\"journal\":{\"name\":\"Berichte der Bunsengesellschaft für physikalische Chemie\",\"volume\":\"102 10\",\"pages\":\"1486-1491\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-03-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/bbpc.199800017\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Berichte der Bunsengesellschaft für physikalische Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/bbpc.199800017\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Berichte der Bunsengesellschaft für physikalische Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/bbpc.199800017","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Kinetics of the Gas-Phase Reaction of NO3 Radicals with 1-Butene, trans-Butene, 2-Methyl-2-butene and 2,3-Dimethyl-2-butene Using LIF Detection
Rate constants for the gas-phase reaction of NO3 radicals with 1-butene, trans-butene, 2-methyl-2-butene and 2,3-dimethyl-2-butene have been obtained in a flow system at 298±2 K and a pressure of 3 mbar He using NO3 LIF measurements. NO3 radicals were produced via thermal decomposition of N2O5 at ca. 400 K, i.e. N2O5+M → NO3+NO2+M.
Applying pseudo-first-order conditions, the rate constants for 1-butene and trans-butene were found to be (1.04±0.11)·10−14 and (3.74±0.45)·10−13, respectively. For 2-methyl-2-butene and 2,3-dimethyl-2-butene the rate constants were obtained under second-order conditions to be (1.03±0.09)·10−11 and (5.49±0.42)·10−11, respectively (unit: cm3 molecule−1 s1).
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