染料敏化太阳能电池用TiO2/单层石墨烯复合光阳极的制备

Jyun-Jia Wang, B. Wang, T. Wu, J. Tsai, T. Meen
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摘要

染料敏化太阳能电池(DSSCs)是一种成本低、工艺简单、前景广阔的太阳能电池。单层石墨烯(G)具有良好的导电性、机械稳定性和热稳定性,可作为DSSCs的光阳极材料。本研究采用tio2 /G复合材料制备DSSCs,并与不同浓度单层石墨烯制备DSSCs的性能进行了比较。然后将单层石墨烯分散制备成DSSCs,并与未分散单层石墨烯制备的DSSCs进行比较。最后,将tio2薄膜与tio2 /G薄膜混合涂覆,分析不同涂覆顺序对DSSCs的影响。结果表明,单层石墨烯可以为电子提供直接传输途径,提高电子的传输速度,减少电子/空穴复合。tio2薄膜和tio2 /G薄膜制备的DSSCs效率最高,为3.6%。将tio2 /G膜与tio2膜混合制备的DSSCs可以略微提高染料敏化电池的效率。与tio2薄膜制备的DSSCs相比,效率略有提高,效率为3.36%。
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Preparation of TiO2/Single Layer Grapgene Composite Photoanodes for Dye-Sensitized Solar Cells
Dye-sensitized solar cells (DSSCs) are low-cost, simple process and promising solar cells. Single Layer Graphene(G) have good electrical conductivity, mechanical and thermal stability, and can be used as the photoanode material for DSSCs. In this study, the DSSCs were fabricated byTiO2/G composites, and compared with the properties of DSSCs which fabricated by different concentrations of Single Layer Graphene. Then the Single Layer Graphene were dispersed and fabricated into the DSSCs, compared with the DSSCs which fabricated by undispersed Single Layer Graphene. Finally, theTiO2 film and theTiO2/G film were mixed coating, and analyzed the effect of different coating sequences on DSSCs. The results indicate that Single Layer Graphene can provide a direct transmission pathway for electrons, which can enhance the transmission speed of electron and reduce the electron/hole recombination. The DSSCs fabricated by theTiO2 film and theTiO2/G film had the highest efficiency 3.6%. The DSSCs prepared by mixing theTiO2/G film with theTiO2 film can slightly improve the efficiency of the dye-sensitized battery. Compared with the DSSCs prepared fromTiO2 film, the efficiency increases slightly and the efficiency is 3.36%.
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