Au/ ni包覆pmma -芯复合颗粒微压缩力学性能及电导率实验

Chao‐Ming Lin
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摘要

本文对各向异性导电膜(ACF)材料中涂覆金属的导电球经平模压缩变形后的力学性能和电导率进行了实验分析。所采用的方法是在导电球中取5个平均直径约为5.65微米的Au/ ni包覆pmma -芯复合球,用单个球进行加载和卸载的压缩行为,获得压缩过程中的抗压强度、变形、电阻、压缩率、回复率等数据。通过理论假设进一步计算了接触半径和接触面积与压缩率的关系。对于接触面积的假设和计算,可以评估平均应力-应变和标称应力-应变的差异,并用于解释导电球变形过程的三个阶段。三个主要阶段为:导电球的初始变形阶段(Cr: 0-0.2)处于小变形弹性压缩区,中期阶段(Cr: 0.2-0.5)为大变形塑性压缩区,部分金属壳破裂,导电球的最终阶段(0.5-0.8)严重分层破碎。结果表明,在压缩比(Cr < 0.5)范围内,导电球能保持10欧姆左右的稳定电阻。这样的电阻(~10欧姆)可以维持稳定的电流传输,这样的平均压缩应力(~300 ~ ~ 750mpa)可以使包金属塑料球的有效回弹力(15 ~ 17mn)。为了有效保持供电稳定性和机械结构可靠性,建议必须将ACF包装内的压缩比有效控制在抗压强度发生前的值(本研究Cr: 0.3-0.5)。
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Experiments on Mechanical Behavior and Electrical Conductivity of Au/Ni-Coated PMMA-Core Composite Particle During Micro Compression Testing
In this paper, the mechanical behavior and electrical conductivity of the metal-coated conductive balls in the ACF (Anisotropic Conductive Film) material after being compressed and deformed by a flat die are analyzed experimentally. The method used is to take five Au/Ni-coated PMMA-core composite balls with an average diameter of about 5.65 microns in the conductive balls, and perform the compression behavior of loading and unloading with a single ball to obtain the data of compression strength, deformation, electrical resistance, compression rate, and recovery rate in the compression process. The relationship between the contact radius and the contact area with the compression rate is further calculated through theoretical assumption. For the assumptions and calculations of the contact area, the differences in the average stress-strain and the nominal stress-strain can be evaluated and used to explain the three stages in the deformation process of the conductive ball. The three main stages are: the initial deformation stage (Cr: 0-0.2) of the conductive ball is in the small deformation elastic compression zone, the middle stage (Cr: 0.2-0.5) is the large deformation plastic compression zone with part of the metal shell rupture, and the final stage (0.5-0.8) of the conductive ball is severely delaminated and crushed. The results show that the conductive balls can maintain a stable resistance of about 10 ohms at a range of compression ratio (Cr < 0.5). Such electrical resistance (~10 Ohms) can maintain stable current transmission and such average compression stress (~300 - ~750 MPa ) can make the effective rebound force (15-17 mN) of the metal-coated plastic ball. In order to effectively maintain power supply stability and mechanical structure reliability, it is suggested that the compression ratio in the ACF packaging must be effectively controlled to the value (Cr in this study: 0.3-0.5) before the occurrence of the compression strength.
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