粘合剂在加氢异构化过程催化剂组成中的作用

K. Abdildina, G. Vassilina, I. Klassen
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摘要

本文采用两种方法合成了基于不同粘结剂含量(分别为80%和65%)的介孔硅酸铝(MAS)的双功能催化剂:第一种方法是将合成的硅酸铝与初步活化的膨润土混合,然后对其进行促进。而第二种方法是先促进合成介孔铝硅酸盐,然后再与膨润土混合。采用湿浸渍法制备了双功能双金属催化剂。采用DRIFT法、TPD-NH3法和标准氮吸附/解吸法研究了其酸性和理化特性。结果表明,采用第一种方法制备的MAS: h -膨润土= 35:65的催化剂样品具有最佳的酸特性和理化性能。
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THE ROLE OF THE BINDER IN THE COMPOSITION OF CATALYSTS FOR THE HYDROISOMERIZATION PROCESS
The authors of the publication synthesized bifunctional catalysts based on mesoporous aluminosilicates (MAS) with different binder contents (80 and 65%, respectively) in two ways: the first method consisted in mixing the synthesized aluminosilicate with preliminarily activated bentonite, which was then promoted. Whereas, according to the second method, the synthesized mesoporous aluminosilicate was first promoted, only then mixed with bentonite. The synthesis of bifunctional bimetallic catalysts was carried out using the wet impregnation technique. Acid and physicochemical characteristics were studied using the DRIFT method, TPD-NH3 and the standard nitrogen adsorption/desorption method. It was found that the samples of catalysts with the ratio MAS:H-bentonite = 35:65, prepared according to the first method, have optimal acid characteristics and physicochemical properties.
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