晶格匹配InGaAs TPV电池余热收集的表征与优化

M. Gamel, P. Ker, H. J. Lee, M. Hannan
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摘要

In0.53Ga0.47As III-V半导体材料因其优异的光学和电学性能而受到热光伏研究界的极大关注。此外,可以在晶格匹配的InP衬底上生长出高晶体In0.53Ga0.47 As结构,使其成为大规模生产的合适候选人。然而,该电池的主要缺点是转换效率低,并且缺乏对废热温度对电池性能影响的详细分析。因此,本工作旨在通过优化有源结和表征不同余热温度(800 - 2000 K)下In0.53Ga0.47 As TPV结构进行综合分析。采用TCAD Silvaco软件模拟TPV电池的输出性能。仿真结果与实验结果相吻合。结果表明,基材厚度的变化对电池的性能有显著影响,当基材厚度从1 μm增加到13 μm时,在辐射温度为1000 K时,电池的效率从6.98提高到18.2%。当辐射温度从800 K到2000 K时,优化后的TPV电池的效率比参考结构提高了10%以上。本研究的结果有助于了解不同余热温度对In0.53Ga0.47As TPV电池性能的影响,并为在不同余热温度下制备高性能In0.53Ga0.47As TPV电池提供有用的指导。
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Characterization and Optimization of Lattice-Matched InGaAs TPV Cell for Waste Heat Harvesting
In0.53Ga0.47As III–V semiconductor material has attracted significant attention from thermophotovoltaic research community due to its excellent optical and electrical properties. Furthermore, a high crystal In0.53Ga0.47 As structure can be grown on a lattice-matched InP substrate, making it a suitable candidate for large-scale production. However, the predominant drawback of the cell is low conversion efficiency, and there is a lack of detailed analysis of the effect of waste heat temperatures on the cell performance. Therefore, this work aims to conduct a comprehensive analysis via optimizing the active junction and characterizing the In0.53Ga0.47 As TPV structure under different waste heat temperatures ranging from 800 to 2000 K. TCAD Silvaco software was used to simulate the output performance of the TPV cell. The simulation results were validated with the reported experimental results. Results show that the variation of base layer thicknesses significantly affect the cell performance, with a significant increase in efficiency from 6.98 to 18.2% at a radiation temperature of 1000 K, as the base thickness increased from 1 to 13 μm. For radiation's temperatures from 800 K to 2000 K, the efficiencies of the optimized TPV cells increased by more than 10% as compared to the reference structure. The results obtained from this study contribute to the understanding of the effects of various waste heat temperatures on the performance of In0.53Ga0.47 As TPV cell, as well as to provide useful guidelines to fabricate high-performance In0.53Ga0.47As TPV cell for various waste heat temperatures.
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