{"title":"生姜提取物对低碳钢的高温缓蚀效果研究","authors":"M. Sohail, F. Hussain, A. Chandio, Maryam Sheikh","doi":"10.24949/NJES.V11I1.266","DOIUrl":null,"url":null,"abstract":"Corrosion is one of the major problems of mild steels in acidic medium. This can be minimized by the application of corrosion inhibitors, however; the most of inhibitors are toxic in nature. Therefore inhibitors from green sources are highly desirable to maintain the sustainability of the environmental system. Consequently, in this study ginger was selected; its juice extracted mechanically and used as an inhibitor. The different concentrations of ginger extract such as 0.25ml, 0.5ml, 0.75ml and 1ml were mixed in 0.1 M HCl solution to record the effect of inhibitor on corrosion rate at room temperature and at an elevated temperature of 50ᵒC. Electrochemical linear polarization resistance (LPR) tests were carried out to determine the corrosion rates at both temperatures with different additions of the inhibitor respectively. The LPR test uses three electrodes, first electrode of AISI 1019 (mild steel), second electrode is standard electrode of saturated calomel while the third electrode consists of graphite, which is called counter electrode, to measure potential difference. The whole assembly was dipped in the solution having varying concentration of inhibitors. The corrosion rate was found to be higher in the absence of ginger- extract. Conversely, the corrosion rate was dramatically reduced more prominently at 50oC but was less effective at Troom; with the trace-additions of ginger-inhibitor. So this research would be the good contribution to overcome the deterioration of mild steel and increase its life at ambient temperatures, by using economically available environmentally-friendly organic compound specially the use of locally available raw material should be focused.","PeriodicalId":338631,"journal":{"name":"NUST Journal of Engineering Sciences","volume":"39 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"High Temperature Effectiveness of Ginger Extract as Green Inhibitor for Corrosion in Mild Steel\",\"authors\":\"M. Sohail, F. Hussain, A. Chandio, Maryam Sheikh\",\"doi\":\"10.24949/NJES.V11I1.266\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Corrosion is one of the major problems of mild steels in acidic medium. This can be minimized by the application of corrosion inhibitors, however; the most of inhibitors are toxic in nature. Therefore inhibitors from green sources are highly desirable to maintain the sustainability of the environmental system. Consequently, in this study ginger was selected; its juice extracted mechanically and used as an inhibitor. The different concentrations of ginger extract such as 0.25ml, 0.5ml, 0.75ml and 1ml were mixed in 0.1 M HCl solution to record the effect of inhibitor on corrosion rate at room temperature and at an elevated temperature of 50ᵒC. Electrochemical linear polarization resistance (LPR) tests were carried out to determine the corrosion rates at both temperatures with different additions of the inhibitor respectively. The LPR test uses three electrodes, first electrode of AISI 1019 (mild steel), second electrode is standard electrode of saturated calomel while the third electrode consists of graphite, which is called counter electrode, to measure potential difference. The whole assembly was dipped in the solution having varying concentration of inhibitors. The corrosion rate was found to be higher in the absence of ginger- extract. Conversely, the corrosion rate was dramatically reduced more prominently at 50oC but was less effective at Troom; with the trace-additions of ginger-inhibitor. 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引用次数: 8
摘要
腐蚀是低碳钢在酸性介质中的主要问题之一。然而,这可以通过使用缓蚀剂来最小化;大多数抑制剂本质上是有毒的。因此,绿色来源的抑制剂对于维持环境系统的可持续性是非常可取的。因此,本研究选用生姜;它的汁液被机械提取并用作抑制剂。将不同浓度的生姜提取物0.25ml、0.5ml、0.75ml、1ml混合在0.1 M HCl溶液中,记录缓蚀剂在室温和50℃高温下对腐蚀速率的影响。通过电化学线性极化电阻(LPR)试验,分别测定了缓蚀剂在不同添加量下的腐蚀速率。LPR测试使用三个电极,第一电极为aisi1019(低碳钢),第二电极为饱和甘汞标准电极,第三电极为石墨,称为反电极,用于测量电位差。将整个组装体浸入具有不同浓度抑制剂的溶液中。在不添加姜提取物的情况下,腐蚀速率更高。相反,在50℃时,腐蚀速率显著降低,但在Troom时效果较差;添加微量生姜抑制剂。因此,本研究将为克服低碳钢的劣化和提高其在环境温度下的使用寿命做出良好的贡献,特别是应重点使用当地可获得的原材料。
High Temperature Effectiveness of Ginger Extract as Green Inhibitor for Corrosion in Mild Steel
Corrosion is one of the major problems of mild steels in acidic medium. This can be minimized by the application of corrosion inhibitors, however; the most of inhibitors are toxic in nature. Therefore inhibitors from green sources are highly desirable to maintain the sustainability of the environmental system. Consequently, in this study ginger was selected; its juice extracted mechanically and used as an inhibitor. The different concentrations of ginger extract such as 0.25ml, 0.5ml, 0.75ml and 1ml were mixed in 0.1 M HCl solution to record the effect of inhibitor on corrosion rate at room temperature and at an elevated temperature of 50ᵒC. Electrochemical linear polarization resistance (LPR) tests were carried out to determine the corrosion rates at both temperatures with different additions of the inhibitor respectively. The LPR test uses three electrodes, first electrode of AISI 1019 (mild steel), second electrode is standard electrode of saturated calomel while the third electrode consists of graphite, which is called counter electrode, to measure potential difference. The whole assembly was dipped in the solution having varying concentration of inhibitors. The corrosion rate was found to be higher in the absence of ginger- extract. Conversely, the corrosion rate was dramatically reduced more prominently at 50oC but was less effective at Troom; with the trace-additions of ginger-inhibitor. So this research would be the good contribution to overcome the deterioration of mild steel and increase its life at ambient temperatures, by using economically available environmentally-friendly organic compound specially the use of locally available raw material should be focused.